As the world began transitioning to Pb-Free solder in the early 2000’s, the electronics industry determined that SAC387 (95.5Sn/3.8Ag/0.7Cu) was the most appropriate alloy to replace eutectic SnPb. While it did have a higher melting point than eutectic SnPb, SAC387 was seen as the best option relative to solderability and usability. The industry quickly shifted to SAC305 (96.5Sn/3.0Ag/0.5Cu) because its lower Ag content resulted in a lower price.
At that time, the industry didn’t realize the performance impact of the Ag content. We now know much more. Ag has a significant impact on a solder alloy's reliability. When thermal cycling higher Ag content SAC alloys (3-4% Ag), the performance tends to be quite good (Ag adds creep resistance to the alloy). However, because of the alloy's rigidity (more Ag - more rigid), it is more prone to brittle fractures during mechanical shock. We achieved significantly improved mechanical shock resistance at the expense of sacrificed thermal cycling performance. The diagram depicts the balance between mechanical shock resistance and thermal cycling performance.
Over the past several years, the Indium Corporation has developed an alloy that minimizes this SAC solder alloy composition compromise. SACM™ is a low-Ag alloy that is doped with Mn. This not only improves the mechanical shock resistance over other low-Ag alloys, it also enhances the thermal cycling performance, making it comparable to SAC305. For more information about SACM™, check out our website at www.indium.com/SACM.
*This post is part of the Introducing SACM™ series.


putational ability, they will be considered human.


Most wave soldering solders have low or no silver. So, about 3% of the 10,000 tons of SMT solder, or 300 MTs of silver, are used in electronics. This is about 1.5% of the 22,000 MTs of silver produced each year. Silver use in electronics does not make anyone’s list of top silver usage.
So electronics solder use since RoHS has not caused tin use to increase, nor is it a significant factor in silver use. Therefore it is highly unlikely that electronics' use of tin or silver has been a prime driver in their stunning price increases in 2011.
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Lets talk about the other issue with using a eutectic solder alloy in SMT: tombstoning. One of the benefits of using the SAC (tin-silver-copper) alloy for SMT and solder paste, is that it has a built-in plastic range, similar to that of Sn62 (62Sn 36Pb 2Ag). It is this plastic range that prevents tombstoning, and takes into account the inconsistent heating of the solder across the part (which is the sole cause of tombstoning). Switching to a eutectic alloy eliminates the plastic range and opens the door for tombstoning.





When was the last time you were in your favorite store and headed toward your favorite aisle only to find that they have rearranged everything? Of course, they do that to attract your attention to different items, but it is only for their benefit.



performed in poorer countries with chemically unsafe processes. RoHS compliant products will save the lives of the unfortunate people who have to perform this type of recycling to survive. 


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