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Can Your Mortality Be Modelled with The Weibull Distribution?

Posted by Dr. Ron Lasky on Monday, October 29, 2012

Folks,

In the last posting, we saw how Weibull analysis helped us to determine that SACM lead-free solder (SAC105 with about 0.1% manganese) has comparable (actually better) thermal cycle performance versus SAC305 solder.  Software like Minitab will give us even more detailed information about the performance of the solder joints in stress testing as we see in Figure 1, above.

 

 

 

In addition to the Weibull plot, we also have the Probability Density Function (PDF), the Survival Function and the Hazard Function.  The PDF tells us when it is most likely that a test board will fail in a test population, as shown by the inserted red line.  We see that it is a little less than 2,000 cycles.  The Survival Function shows the percent of surviving test boards.  We observe that the expected life (the 50% point) is quite close to the maximum of the PDF.  The Hazard Function tells us the rate at which the test boards are dropping out.  It increases with time, but there are few boars left so the PDF drops down at the end of the test, even though the fall out rate is the highest.

 

 

 

 

It is interesting (and perhaps appropriate as Halloween approaches) to consider if human mortality follows a Weibull distribution.  I used some data for the Centers for Disease Control  that are a little over ten years old, for males in the US.  So, the mean life expectancy is a little low at 72 years.  (I was a little lazy, the old data were a little easier to work with than new data, some conversions are needed to make it work.) The data appear above in Figure 2. 

 

As you can see, just like a solder joint, your life expectancy can be modeled quite well by the Weibull distribution.

Cheers,

Dr. Ron

 

 

 

 

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Choosing the Best Metallization for your NanoBond® Application

Posted by Jim Hisert on Monday, October 29, 2012

Since the NanoBond® process is almost instantaneous, fluxes are not used. (They just don’t have enough time to heat up to their activation temperature and remove oxides.)

So, because this is a fluxless soldering application, surface choice and preparation become very important. We no longer have the chemical power of a flux to break down surface oxides, instead we must make sure our surfaces are ready to be joined.

The first choice to make is: will you have solder on the parts to be bonded, or will you use solder-coated NanoFoil®?

If you decide to use bare NanoFoil®, the parts must have a solder finish such as pure indium, SAC 305, or tin. If you choose to use a solder-coated NanoFoil®, you can bond gold and silver metallized parts.

 

Need help figuring out what to do? Ask us: AskUs@indium.com

*This post is part of the NanoBond® Process series

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Weibull Analysis of Solder Joint Failure Data II

Posted by Dr. Ron Lasky on Wednesday, October 24, 2012

Derivation of the Weibull Graph

Folks,

Last time we introduced Weibull analysis. Let's now derive the relationships needed to calculate the slope, beta, and characteristic life, eta.

F(t) is the cumulative fraction of fails, from 0 to 1. By choosing Ln(t) as x and LnLn 1/(1-F(t) as y, we would expect a straight line.  See the derivation above.  It can be shown graphically that this fact is so.  So if we plot F(t) versus t on logarithmic graph paper, the slope of the line will be beta. To determine eta, let t=eta, in the first equation below.  The result is F(t) = 1-e-1 = 0.632.  So the time at which 63.2% of the parts have failed, is eta, the characteristic life.

Let’s consider some data comparing SAC305 and SACM (SAC105 with about 0.1% manganese) BGA solder balls in thermal cycle testing.   The primary test vehicle employed was a TFBGA with NiAu finish mounted on PCB with OSP finish.  SACM is a new breakthrough soldering alloy that has better drop shock resistance than SAC105 and comparable thermal cycle performance to SAC305.  The data follow.  The first column is the sample number, the third and fifth columns are the number to thermal cycles to fail for SAC305 and SACM.  The second and forth columns are rank of the sample number.  One would think that the first number in the second  column would be 100*(1/15) =6.67%, as it represents the cumulative percent of samples failed, but a slight correct factor is needed.   By plotting the log log of rank as shown above (LnLn1/(1-F(t)) vs log of cycles at failure, we get the Weibull plot.  The slopes of the best fit line is equal to beta and the number of cycles at rank = 63.2% is eta.

 

Fortunately software like Minitab 16 does the plotting and calculating of beta and eta automatically.  The results are below:

We see that the shape (beta) for SAC305 is 1.76 and that of SACM is 6.09, the scale or characteristic life (eta) is 1736.8 and 2016.8 respectively.  These results are a strong vote of confidence for SACM.  Its steep slope (high beta) suggests a tighter distribution, with more consistent solder joints and its characteristic life (eta) is also slightly greater.

I plan on teaching detailed workshops on this topic.  I will keep you posted.

Cheers,

Dr. Ron

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Calculating Solder Paste Usage

Posted by Christopher Nash on Monday, August 20, 2012

Calculating the exact amount of solder paste needed for a given circuit board or for a full production run can be difficult for several reasons, including:

  • print deposit variations
  • paste left on the stencil and squeegees after the build is complete
  • bead size needed for the build (which depends on the squeegee size)

The theoretical volume of solder paste can be calculated for each board using the Greely Formula and a simple volume calculation.

The Greely Formula:

Specific Gravity of the flux vehicle is generalized to 1. 

Example:

  • Solder Paste: SAC305, Indium8.9HFA, Type 4.5, 87.75%
  • Aperture Size: 0.012” Square
  • Stencil Thickness: 0.004”

 

 

 

 

Solder Paste Specific Gravity = 4.14

 

Volume for this aperture can be calculated using the following formula:

Length x Width x Height

0.012” x 0.012” x 0.004” = 0.000000576 inches3

 

To get the theoretical weight of the solder paste for the 0.012” square aperture you must multiply the solder paste theoretical volume by the solder paste density. 

 0.000000576 inches3 * 4.14gm/cm3 = 0.000009439cm3 * 4.14gm/cm3 = 0.0000391gm

 

To calculate the theoretical amount of solder paste that will be used for each board, the weight of solder paste for each aperture on the board will need to be calculated.  Once all of the weights have been calculated they can be added together which will result in the amount of solder paste per board. 

Of course this is the theoretical value and not an actual value.  The easiest way to determine the actual paste weight per board is to weigh a board before the paste has been printed and then again after the paste has been printed.  The difference is the actual solder paste weight or consumption of solder paste per board. Of course, there will be some margin of error even in this calculation due to the weight tolerances of the board and the variations in solder paste deposits from print to print.

Let me know if I can help you calculate or estimate the amount of solder paste your project will consume.
Chris

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Musings on Electronics Assembly Metals: Gold Unified a Country

Posted by Dr. Ron Lasky on Monday, June 25, 2012

Folks,

In Ken Burn’s  excellent miniseries The Civil War, Shelby Foote states that the Civil War  made us a country by uniting North and South.  He argues that before the War, its citizens might say the United States are a good place to live, noting the feeling of separation. He points out that before the Civil War, most people had never traveled more than 30 miles from where they were born and therefore had only a theoretical notion of the US as a country. During the War, millions of men and women had walked its fields and hills and cast their eyes on her valleys. They came home with a solid feeling for what this great land is. So, today, everyone, North and South, would say the United States is a good place to live.    

If the Civil War united us North and South, gold united us East and West. Shortly after the Louisiana Purchase  in 1803, President Thomas Jefferson commDuctility of Goldented that it would take 25 generations (a little more than 500 years) to settle the West.  Most of us today would balk at this estimate, yet in 1803 it was very reasonable.  Consider that by 1803, the US had been settled for 200 years and the vast majority of people lived with a few hundred miles of the Eastern seacoast.   Yet by 1850 California had become a state and twenty years later the country was united East and West by the transcontinental railroad .  The sole driving force for these amazing events was gold. Gold was discovered in 1848 at Sutter’s Mill and within months the California gold rush  had begun.  By 1855 more than 300,000 people had come to California from all over the world.  It was the biggest gold find in the world up to that date, but, to put it in perspective, only 750 metric tons (MT) of gold were mined in 10 years of this Gold rush.  All of this gold would only be a cube only 3.4 meters (11.1 feet) on a side. This fascinating story is documented in The West, another documentary produced by the prolific Ken Burns.  

Today over 2,000 MT of gold are mined each year, worldwide.  Modern mechanized and automated mining techniques enable this tremendous increase.  About 75 percent of all of the gold mined in the world has been mined in the last 100 years or so.

Today, about 50% of gold is used for jewelry, 40% for investments, and 10 % for industrial uses.  Gold has one of the best surface electrical conductivities of any metal, making it a top choice for high-performance electrical contacts.  Its resistance to corrosion enables gold solders to be very robust in harsh environments.  Gold’s malleability and ductility also make it ideal for bonding wires  in semiconductor packages.  Gold is so ductile that a 0.5mm diameter ball can be pounded out into 0.5 square meters of gold leaf (see the image).  In electronics assembly, gold is used in Electroless Nickel Gold (ENIG) surface finishes for PWB pads and some corrosion resistant, mechanically-strong solders.  Some gold solders have tensile strengths seven times greater than SAC305.  With their 280C liquidus temperature, these robust solders can also be used in high temperature applications.

But remember, without the California Gold Rush of 1849, and the Alaskan Gold Rush of 1897, the United States would be a dramatically different country today  indeed.

Cheers,

Dr. Ron

 

Image source.

 

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Tombstoning: The Death of a PCBA

Posted by Eric Bastow on Wednesday, November 30, 2011
Tombstoning DiodeTombstoning (also known as the Manhattan effect, drawbridge effect, or Stonehenge effect) is described (in the simplest, and most common, sense) as occurring when one end of a passive device, such as a resistor or capacitor, rises up out of the solder and breaks contact with the circuit. But it is not limited to passive devices. Other surface mount devices can tombstone as well (see the tombstoning diode image - top). Tombstoning is a "fatal" defect because it produces an open circuit.

Tombstoning has, once again, become a central issue - primarily due to two main issues:
  • Tombstoningthe transition to Pb-Free (higher reflow temperatures, and related flux issues)
  • miniaturization (0201s and 01005s)
Tombstoning is almost always the result of uneven wetting forces on the terminations of the component. When one end "wets" before the other, the (now unbalanced) wetting force of the solder "pulls" the component, rotating it, causing it to stand on end.

Various factors contribute to tombstoning. The one that we (as a solder paste supplier) typically encounter  is uneven heating of the PCB assembly - which causes one paste deposit to melt and wet before the other - per component (as described above). Trying to achieve a higher reflow temperature, as required with the new mainstream Pb-Free alloys, can exacerbate the greater thermal gradient across the PCB (and from one end of a component to the other).

Reflow ProfileThermal gradients are usually easily remedied with minor adjustments to the reflow profile:
  • The reflow oven operator can slow down the ramp rate. A slower ramp rate allows for more uniform warming of the PCBA.
  • Another technique is to employ a "soak" just below the melting temperature (solidus) of the alloy. For example, for a SAC305 profile (217°C solidus), one may implement a "soak" at 205 to 210°C for 30 to 120 seconds. This allows for the cooler parts of the PCBA to "catch up" to the warmer parts. After thermal equilibrium has been achieved, one can spike the temperature up to the appropriate peak temperature (i.e. 245°C). This technique (depicted in the reflow profile shown at the right) allows for all of the solder paste deposits to melt and wet the component terminations at roughly the same time; thereby, mitigating tombstoning.



Different flux chemistries, and types, can also impact tombstoning. It is often desirable to have a solder paste that wets well, even to old, oxidized components. One possible negative side effect of an excellent wetting solder paste is tombstoning. When the paste wets "aggressively" to the component terminations, causing a strong wetting force, even the slightest disparity (temperature, cleanliness, flux area, etc.) from one termination or pad to the other can cause the component to tombstone.

The wetting speed and force is also directly related to the rate at which the solder melts. It should be obvious that wetting only occurs when the solder is in a liquid state, not while solid. For this reason, solder alloys that are not eutectic (alloys that start to melt at one temperature but are not fully liquid until some higher temperature) can produce less tombstoning than a eutectic (clearly defined melting point) alloy, all other things being equal. Sn63 (63Sn 37Pb) is a eutectic alloy and makes a clean transition from a solid to a liquid at 183°C. Sn60 (60Sn 40Pb) is not eutectic and starts to melt at 183°C but is not fully liquid until 191°C. In the case of "non-eutectic" alloy like Sn60, between 183°C and 191°C, solid and liquid are coexisting. To this end, some solder paste manufacturers have developed alloys that melt gradually (are purposely not eutectic) to combat tombstoning.  

Wetted Passive ComponentThe pad design and lay-out can also affect tombstoning. Usually pads that are located mostly beyond the terminations or have large pad areas beyond the terminations can contribute to tombstoning. To the left is an image of a cross section of a soldered passive component. Notice how the solder fillet reaches to the top of the termination. Solder paste deposits that extend well beyond the component cause a lot of wetting force and leverage to be applied to the extreme ends and tops of the component. This wetting force, if not evenly applied to both terminations, can cause the component to tombstone.









Reduced Solder VolumeSimilar to the placement of the solder paste deposit (pad design), solder volume can also impact tombstoning. It is very simple. More solder equates to more wetting force and vice versa. To the right is an image that has an extremely reduced amount of paste volume (not recommended to this degree). If one could imagine that this component had indeed properly soldered to the pads, one could see how it would be nearly impossible for the component to tombstone. There is simply not enough solder to wet the entire end of the termination. Solder deposit volumes that restrict the solder from being able to wet up to the top of the component greatly reduce the wetting force and leverage that the solder can apply to the component. Depending on the class of workmanship that one is building to, it may not be practical to reduce the solder volume. The product class may require fully wetted terminations.



It is also critical that the solder paste deposit and component sit squarely on the pads. Any offset can affect the way the solder wets the terminations and can cause tombstoning.

Offset Solder Paste Deposit


Miniaturization, as characterized by smaller, lighter passive components, such as 0201s and 01005s, creates a struggle where tombstoning is concerned. Issues of solder paste deposit location (see image to the right), component placement, and solder paste volume are difficult to control given the overall minuscule scale of the scenario. Also, smaller components are inherently lighter and, therefore, easier to pull up on end.

Controlling tombstoning is a critical issue in SMT assembly. But, with understanding what causes tombstoning, one can control it.

CONTACT ME to discuss tombstoning:

Eric Bastow: Senior Technical Support Engineer

Phone: +1.315.853.4900
E-mail: ebastow@indium.com

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低温合金在感恩节之中的应用 Low-temp Alloy Used In Thanksgiving Holiday

Posted by Anny Zhang on Tuesday, November 29, 2011

turkey timer with low temp solder alloy上周是感恩节。根据美国的习惯,我们拷了一只火鸡Turkey来庆祝。

平时向客户们介绍我们公司的preform预成型焊片这一大产品系列时,我们经常会用这个有趣的故事:你们知道这个细条小圆柱形的焊片用在哪里吗? 感恩节的火鸡里!其实是pop-up turkey timer。 在全美销售火鸡和火鸡测温器的厂家,都可以大量地使用我们这种低温合金的焊片。每年感恩节烤火鸡,大家会把timer插在火鸡里面,等火鸡里面也达到一定温度(熟了),在timer里面的低熔点合金(含有铋金属Bi/Bismuth)就会融化膨胀,使其里面的弹簧自动跳起来。

Bi58Sn42是一种很常用的无铅低温合金。它可以用在散热器heat sink/heat pipe的焊接上,也可以用在电路板的印刷焊接上。有些客户板子上的某些元部件有不能承受超过1800c 或是1900c(Sn63Pb37的熔点是183C,SAC305是217C),所以就常会用到BiSn锡铋合金。或是分温度层(step soldering)焊接,也会用到这种低温合金。 锡铋这两种金属的价格虽然随着市场大宗商品价格的变动有些变动,但是和贵金属金银等相比,价格还算可以。

铋是一种很脆的金属,所以锡铋BiSn的韧性不够。但是如果加上1%的银,Bi57Sn42Ag1,就可以大大提高合金的柔软性和韧性了。

Cheers!



Pic: Google Image

PS: 上周我给加拿大的客户发邮件,不小心顺手写了祝感恩节快乐的语句。后来一点击发出后,就马上后悔了,因为我突然想起加拿大人感恩节不是在11月,而是在10月份。因为加拿大更加靠北边,他们的粮食收成季节早过美国,所以也提早庆祝感恩节…好在其中一个加拿大客户还挺幽默的,马上回复了我的邮件,祝我们这里感恩节快乐

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锡膏中的金属比重(Metal Load in Solder Paste)

Posted by Anny Zhang on Tuesday, August 30, 2011

Indium Solder Paste前段时间有个客户说Indium3.2的印刷性能很不好,锡膏在印刷时的滚动不行,而且还堵塞网孔。Indium3.2是一款水洗性的无铅锡膏。

我们详细问了客户一系列问题后,发现客户用的这款产品SAC305, Type4 powder,金属比重居然有89.5%。根据我们对产品的了解和时间,89.5%的金属比重远远高于我们公司推荐的。这应该就是问题所在。于是我们马上建议了新的金属比重的Indium3.2.

焊锡膏中一般有50/50体积比的金属和助焊剂,重量比大约为90/10。 各个公司不同产品的金属含量比重都会有点差别。但正是这细微的差别,很可能就是产品性能最佳表现决定的关键。比如说3号金属粉和4号金属粉的差别,因为4号粉的表面积比3号粉多,需要更多的助焊剂来“清洗”金属球表面的氧化物,所以4号粉的金属比一般会比3号粉低一点点。金属比的不一样,也会使锡膏的viscosity黏度不同,这会影响印刷时的表现。

Cheers!

Pic:Indium Corporation

PS: 上周看了US Today报纸中的一篇报道“’Made in China’ benefits U.S.”这还是我第一次看见老美自己写出报道,公开说认识到了中国制造其实是在多方面对自己国家有利的;而不是以前老说的中国制造削弱了美国的制造业,抢走的美国的就业机会,等等。如果你看到报道上说的数据,每1美元中国制造的产品,有45美分是给了中国(产品的物料成本,中国人民的劳动力,土地,各种资源等),还是55美分是进美国人自己的口袋(营销,渠道,和售后服务)!!郎咸平是这方面的专家,好久没有看他的书了,最近要温故一下了。 

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焊接材料使用在医疗器械上

Posted by Anny Zhang on Thursday, July 14, 2011

上来扫尘了!前段时间生了个大胖小子,所以从怀孕到破腹产,见识了很多美国先进的医疗器械,联系到平时销售工作中了解到的客户成品,有些感慨“原来成品长这个摸样, 是这样使用的”!幸运也好,或是有些“不幸”吧,成品用在了我身上。

在电子制造加工行业(Electronic Assembling Industry),亚洲很多工厂都是在做high volume, low mix 的产品,特别是computers, consumer devices & communication发面。 美国和西欧的工厂,更多是做high mix, low volume, 比如说医疗器械。

医疗器械的产品,直接涉及到生命安全,而且大部分都是long life span的,所以对可靠性(reliability)的要求十分高。 这也使很多加工医疗器械产品的工厂对焊接材料的选择和测试要求很严格,特别是对焊锡膏(solder paste)。

大件的没有和人体直接接触的医疗器械板子,很多都还是在用有铅SnPb焊接材料,比如说我这次生产前使用的超声波测试仪,监视宝宝心跳和我宫缩的测试仪,都应该还是有铅板子。不过很多医疗器械的客户们都在密切关注着2014年RoHS2对这方面的要求;客户们也在密切做准备,评估无铅材料,来应对届时的变化需求。

和人体有直接接触的医疗器械,很多都已经是无铅了。 前段时间有个客户生产一种一次性心跳读数器heart rate reading device,板子的形状像一个很小的婴儿鞋子,只有成人手掌的1/4大小左右,而且十分薄。当时就使用了我们的SAC305 焊锡膏和solder preforms (预成型焊片)。据说这种携带型小仪器可以扣在衣服上读病人的心跳,读出的数据直接通过wi-fi传送到医院的数据中心进入系统;医生和医院就可以随时随地远程收集病人的数据……

世界人口在不断地增多,也在不断地老龄化(aging population),这使对医疗器械的需要在增加。这应该是一个有前景的大行业,也希望大家都能享受到这些科技进步带来的便利,益寿连年。

Cheers!

Read Baby's Heart Rate

Pic: Google Image

PS: 还是那句我喜欢的话“生命在于运动(一下)”。和身边很多孕妇朋友相比,我才发现原来自己从小坚持和热爱运动在怀孕和生产过程中帮了那么大忙,生之前那一天我妈妈还在感慨说我走路一小时都还是健步如飞的,哈哈:-)

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Indium公司在 Nepcon上海将举行SAC105+Mn记者招待会

Posted by Anny Zhang on Wednesday, May 11, 2011

下周在上海将会有SMT行业中一年一度的大盛事,Nepcon上海展会。 

Indium 公司将在5月12号周四上午11点,在展位2E06举行一个关于SAC105+Mn的记者招待会。

Indium公司几年前就研发了关于SAC105+Mn的合金,并申请了专利。这里有相关的文章“Achieving High Reliability Low Cost Lead-Free SAC Solder Joints Via MN or CE Doping
”与您分享,由Indium公司的Dr.Weiping Liu 和 Dr.Ning-Cheng Lee李宁成博士等共同著作。  

这些年来随着金属成本的上升,中国市场对低银的可靠性高的焊接材料的需求,Indium公司也对SAC105+Mn的焊锡膏等焊接材料做了一系列的研究。实验数据表明,用SAC105+Mn合金做出来
的焊锡膏,跌落测试(drop test)比SAC305好很多,热循环测试(thermal test)与SAC305媲美。目前已经有相当一部分中国客户在使用这款焊锡膏了,工厂的产率与原来用SAC305时的相差无几。
更多的信息,我们将于您在记者招待会上分享。热切期待届时与您相见。

Cheers!

SAC105 + Mn paste
problem-solved_Great performance in drop test

Pic: Indium Corporation

PS;我以前在博客中也与大家分享过几篇关于SAC105+Mn的小文,请看这里1,2。谢谢您持续的关注!今年宝宝快出生了,不能与您在Nepcon上海中相聚,盼来年再见!

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日益增长的金属价格(锡 Tin,银Silver)

Posted by Anny Zhang on Tuesday, April 19, 2011

从去年年中到现在,由于国际原油价格的连续上涨,带动了大宗商品包括金属价格的飙升。近期的利比亚动乱,使情况进一步“恶化”。

我们常有的锡铅SnPb63/37焊锡膏,和无铅锡银铜SAC305焊膏,都含有锡,SAC305还含有3%的银。根据下面的图片,不难看出锡的价格比去年年中涨了近两倍,银的价格更是涨了两倍多。这都使焊锡膏Solder Paste的金属成本上升了。随着原油和大宗商品的价格上升带来各国一定的“通货膨胀(inflation)”, 大家也应该发现,生活中各种商品的价格也有攀升。同理,焊接材料(solder materials)的运输成本,包装成本,劳动力成本,企业运营经费等都跟着上涨。

Sn Price Apr 19 2010-Apr 19 2011, USD/TON
Silver Price 2010
Silver Price 2011

虽然Indium Corporation的主营焊接材料现在面临一定的成本挑战,但是我们还是采取积极的方法, 在保证品质和服务不变的情况下,给客户们提供物美价优的有竞争力的产品!

Cheers!

Pic:
1. www.lme.com
2&3. www.kitco.com

PS:国内的亲友们都“抱怨”物价的狂涨,美国这里又何尝不是呢。

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Status of Lead-Free Solder Joint Reliability in Thermal Cycle Testing

Posted by Dr. Ron Lasky on Tuesday, February 1, 2011

Folks,

Back in October, I posted comments on lead-free reliability.   In this post, I mentioned that I chaired a session at SMTAI on “Alternate Alloys”. At this session, Greg Henshall presented a paper on the  Low Silver BGA Sphere Metallurgy Project. This paper was a collaborative effort of six companies.  In addition, Richard Coyle presented an overview of the work of three companies titled “The Effect of Silver Pb-Free Solder Joint Reliability in Thermal Cycling Testing.Content on the Solder Joint Reliability of a Pb-free PBGA Package.” Both projects evaluated lead-free thermal cycle reliability as a function of silver content and compared the results to SnPb reliability.

Both papers concluded that, as far as 0oC to 100 oC thermal cycle reliability is concerned in their experiments, SnPb < SAC105 < SAC305 < SAC405

Coyle’s presentation summed it up best:

“Each of the SAC alloys outperformed the SnPb eutectic alloy in every test, including the long, 60 min. dwell time test. This tends to diminish the argument that SAC is less reliable than SnPb.”

To be clear, it was two papers by two different groups coming to the same conclusion. It would probably be a stretch to say that the conclusions of either group were “almost unique".

Denny Fritz responded to this blog post with this point:

“No one I know will dispute your ranking of SAC better than SnPb solder using the commercial temperature cycle Henshall uses – 0C to 100C. But, harsh environment electronics have to perform to either -40C or -55C, and most use a top end cycling temperature of 125C. IT IS IN THAT WIDE THERMAL CYCLE TESTING THAT SnPb outperforms SAC solders.”

Denny’s point is well taken. I believe it can be said that SAC alloys have demonstrated acceptable reliability in commercial, non harsh environments (i.e. mobile phones, PCs, consumer electronics, etc.) However, it cannot be said that acceptable reliability for SAC has been established for military (RoHS exempt) and harsh (i.e. automobile engine compartment) environments.

A short time ago, Werner Engelmaier wrote an article on this topic (Global SMT Vol 11, No. 1, Jan 2011, pp 38-40.), which among other things he said:

 

“Of course, ‘Dr. Ron’ selectively picks data agreeing with the point of view he held from the inception of the Pb-ban under RoHS on a plot with an expanded x-axis overemphasizing the differences and supporting a solder joint reliability ranking of SnPb < SAC105 < SAC305 < SAC405.”

 

Ouch! My motives were not quite so nefarious, I chaired a session and wanted to share the conclusions.

 

However, Werner makes good points in his article, data exist disagreeing with this reliability ranking and he suggests some good points on how to conduct reliability tests so that comparisons can be made between data sets.

 

In reading some of his other articles, I was delighted to find that we actually agree on the state of lead-free reliability in thermal cycle testing. Here is a statement of his circa 2008 (Global SMT, Vol 8., No. 8, Aug 2008 pp 46-48.):fting, and n

 

“It has been 2 years since the infamous ban of Pb-solders under RoHS. What have we learned? For solder joints, no dramatic differences in reliability are apparent. The data bases for LF-solders have grown, the favored LF-solders might be shifting, and no reliability model exists as of yet. Nevertheless, progress has been made.”

 

Cheers,

 

Dr. Ron


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锡银铜105 (SAC105 with Dopants) Pb-Free Solder Alloys

Posted by Anny Zhang on Tuesday, November 30, 2010

过去半年,因为某些国家的“宽松货币政策”大量印钞票,弄得和国际大宗商品的价格一路攀升。和我们行业直接相关的就是金属原材料的价格,特别是锡银铜的价格。

锡银铜是无铅合金的主要成分,虽然其中银在现在最常用的SAC305中只占3%,但是其价格的一路攀升,也使SAC305的金属成本价格随之一路狂飙!

Silver Price

为了更好为客户们提供具有成本优势(cost-effective)的可靠性强(reliable)的好用的焊接材料,Indium公司早就在低银合金上做了很多的研发,请看这里的相关Indium论文“Achieving High Reliability Low Cost Lead-Free SAC Solder Joints Via MN or CE Doping”

by Dr. Weiping Liu, Dr. Ning-Cheng Lee, Adriana Porras, Dr. Min Ding, Anthony Gallagher, Austin Huang, Scott Chen, Jeffrey Chan 

最近,我们的一些客户适用了Indium
的SAC105 with Mn 焊锡膏(solder paste),发现其性能在各种应用上都表现良好(空焊盘,chip料,屏蔽罩,细IC间距,BGA等), 其印刷性,润湿性,爬锡,焊点的光亮度,BGA空洞的比例等,都和SAC305一样好或是十分接近。

SAC105 w Mn solder paste performance

更详细的资料或是信息,欢迎随时联系我们china@indium.com, askus@indium.com .

Cheers!

Pic:

1. www.kitco.com

2. Acknowledge to a South China customer; beta test pictures 


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Lead-Free Solder Thermal Cycling & Drop Shock Reliability is Looking Good

Posted by Dr. Ron Lasky on Sunday, October 31, 2010

Folks,

I was at SMTAI (Surface Mount Technology Association International) from September 24 and 27, 2010.   As I mentioned, I chaired a session on Alternative Alloys from 2:00-3:30PM on Tuesday 26th.


At this session, Greg Henshall presented a paper on the Low Silver BGA Sphere Metallurgy Project. This paper was a collaborative effort of six companies. In addition, Richard Coyle presented an overview of the work of three companies entitled The Effect of Silver Content on the Solder Joint Reliability of a Pb-free PBGA Package. Both of these projects evaluated lead-free thermal cycle reliability as a function of silver content and compared the results to tin-lead reliability.

 

Both papers concluded that as far as thermal cycle reliability is concerned SnPb<SAC105<SAC305< SAC405. Coyle’s paper summed it up the best:

 

Each of the SAC alloys outperformed the SnPb eutectic alloy in every test including the long, 60 minute dwell time test. This tends to diminish the argument that SAC is less reliable than SnPb. (See Coyle’s figure. Data curves to the right are more reliable.)

Henshall’s paper also showed that the addition of dopants, to improve shock resistance, in SAC105 does not reduce thermal cycle life.

 

So, it appears, at this time, that, from a thermal cycle and drop shock perspective, it is looking more and more like SAC based solders out perform tin-lead solders in these two reliability arenas.

 

At the end of the session a noted lead-free curmudgeon came over to introduce himself.  We have had a jovial disagreement on several blogs etc. in the past re: lead-free status and issues, but had not met in person.   I should mention that this person is a college graduate, a former technical leader at several influential technological companies, and he owns a PE license. I asked him what he now thought about lead-free reliability after hearing the talks. He claimed that he is a little less likely to think that lead-free reliability is a disaster. He still refuses to purchase any lead-free products. He buys old units (pre-2006) on eBay.

 

I mentioned that over $2 trillion of electronics has been placed in the field since 2006 with no unusual reliability issues.   I then went on to say that a RoHS-compliant product is much more likely to fail due to a non-RoHS related issue. He did not disagree. So then I asked him why he won’t use RoHS compliant electronics. His answer: “I just don’t trust them.”

 

Cheers,

Dr. Ron
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SAC105 with Mn 锡银铜105加猛合金

Posted by Anny Zhang on Thursday, September 30, 2010

由于近期金属原材料的价格高涨,越来越多的客户都向我们询问低银合金的焊接材料。 Indium公司研究SAC105 with Mn合金有好一段时间了;本公司的李宁成博士Dr.Ning-Cheng Lee和刘伟平博士Dr. Wei-Ping Liu也曾经发表过关于这个合金的论文。

 

在SAC105 with Mn合金中, 我们主要关注这两点: 合金的抗低落测试(drop test),和热循环测试(thermal cycle test).

 

抗低落测试,主要是针对手机的焊接组装需求。 因为SAC105中只含有1%的银,而不像SAC305中含有3%的银,所以不但价格便宜了不少,而且solder joint也更加坚硬。如果你看IMC的切层图片,可以看见SAC105 with Mn有更加薄和平滑的IMC层,IMC层的晶粒也更加细微。

 

热循环测试,这是对合金可靠性(reliability)的一个要求。一般的SAC合金,如果含银量高些,热循环测试的效果也会好些。在SAC105 with Mn中, Mn的加入可以阻止IMC层晶粒在热循环中随着时间的推移的长大、粗化。

更多的相关信息,欢迎随时联系我们 askus@indium.com .

 

Cheers!

Pic: Paper of “Achieving High Reliability Low Cost Lead-Free SAC Solder Joints Via MN or CE Doping” By Dr. Ning-Cheng Lee, Dr. Wei-Ping Liu, and other co-authors.

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給客戶帶來價值(Add Value To Your Customers)

Posted by Anny Zhang on Thursday, September 2, 2010

最近小忙,少讀書了,也少和大家分享了;不過工作之餘,翻看了一下《A Seat at The Table》一書,覺得裏面有些道理也蠻有啓發的。比如説此書中一直圍繞這個主題來展開了論述“Today, the only thing your customer cares about is value.”

就這個觀點,再對照一下Indium公司的兩個主要系列產品:

²       電路板組裝焊接材料(Solder Materials):  這裡也要分產品而論。對於技術含量較高,工藝使用要求較多的焊錫膏(Solder Paste)材料,重視成品可靠性的客戶們會更多的關注產品帶來的“價值”。 如果只圖便宜的材料,但是用起來“錯漏百出”的,最後還是事倍功半:返工,復修,廢棄率高(特別是浪費貴的不能翻修的板子),產出率低,總體成本也自然高了。 對技術含量較低,工藝已經“模式化”的產品,像錫棒(Solder Bar),錫綫(Solder Wire),  性价比會更關鍵……在目前日益高漲的金屬原材料市場中,Indium公司考慮到客戶們的成本壓力,也推出了性能可以和SAC305錫棒媲美的有成本優勢的Sn995錫棒。

 

²       半導體封裝材料(Semiconductor Materials):  整個半導體行業應該算是一個高成本,高投資,高回報(運營得好的話)的三高行業。半導體封裝材料也像是其中的經絡血脈吧,連接各個部分,讓整體最後順暢無阻的工作。半導體各個部分的材料都不便宜,設備更是不菲;對材料性能的表現要求和驗證都很嚴格,畢竟都投資那麽多,不能“功虧一簣”嘛。所以客戶們一般會十分重視產品的價值。 Indium 公司目前提供的半導體材料有:Wafer Flux, Wafer Paste, Micro Spheres, Flip-Chip Flux, Substrate Paste, Ball Attach Flux, Die-Attach Paste/Wire, PoP Fluxes, etc. 

 

Indium公司還為大家提供散熱界面材料(Thermal Interface Materials),工程焊料(Engineering Solders),薄膜光付太陽能板製造材料&太陽能板組裝焊接材料(PV Solar Materials),和銦金屬及其化合物等。 這些材料使用在比較領先的應用中,新興行業,或是細分市場中,客戶們都十分重視產品和服務能給自己帶來的價值。


Cheers!  




Pic: Indium Corporation


PS:
前些日子看了中央4台的《第三屆漢語橋在華留學生漢語比賽》,感慨不已!除了感嘆這些留學生們對“那麽難”的漢語的精湛掌握,對中國文化和歷史的了解,甚至對中國的熱愛;更感慨的是,這些活動也説明了祖國的強大!現在越來越多的留學生們來中國學習,想進一步了解中國,和中國人民交流;中國話也在慢慢傳播到全世界!以前中國學子們苦讀英語,考TOFEL, 雅思,GRE什麽的;現在金髮碧眼的學生們也在場上比拼誰更了解我們的“四書五經”了,哈哈!

 

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NanoFoil® on Wikipedia

Posted by Tommy Acchione on Friday, August 13, 2010
NanoFoil® is on wikipedia!

Link - en.wikipedia.org/wiki/NanoFoil

 No, we are not responsible for the post, but this is when you realize you've got something special.  Someone out there took the time to write information and do some research about the technology so that the next time you hear the word NanoFoil® and google it, you have a referenced definition.

Wikipedia is the new Encyclopedia Britannica for the internet generation.  Except now, instead of buying lettered tomes as they come out, or waiting for an updated reference to a topic like SAC305 solder material (or for those not solder inclined say Australian Koala Bears), we now have instant gratification.

Now I can't talk about the great things about wikipedia without talking about the concerns.  Being an open forum type encyclopedia, and with thousands of posts being updated daily, there is a lot of room for error.  Many of us young enough to have wikipedia available to us in College remember being told that we could, under no circumstances, use wikipedia as a reference. But now, with Wikipedia's stricter policies on articles, this may soon change, if it hasn't already.

What I can confirm is that this NanoFoil® post is 99% accurate!  The numbers are off by a few percentage points here or there but, for the most part, it is informative and useful.

So what do you think of wikipedia?  Has it made us smarter and able to process and learn more information, or has it made us reliant on "suspect" information?
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Sn995

Posted by Anny Zhang on Tuesday, July 27, 2010

最近的客戶拜訪中,大家都對Indium公司的新焊錫棒(Solder Bar) Sn995十分感興趣。 Sn995是一種無鉛的焊錫材料,不含銀,主要成分是99.5%的Sn, 大約0.5%的Cu, 還有一些微量元素。Sn995的主要微量元素,是Cobalt 鈷 (Co)。

先在市面上的無鉛焊錫棒,除了SAC305, 也有很多SnCu+Ni的材料。在我們各種可靠性試驗中,都發現“Cobalt is a better grain refiner.”

²       Functional Test 整板功能性測試

²       Thermal Cycling Test 熱循環測試

²       Intermetallic Growth Test

²       Wetting Test 潤濕測試

²       Shear Test 剪切力測試 

²       Pull Test 拉力測試

²       Accelerated Aging Test 老化測試

²       Hole Fill test 填孔測試

²       Copper Loading Test

²       Dross Test


在以上的所有測試試驗中,
Sn995 都呈現出相同或是更好的性能。進一步的詳細測試信息,歡迎隨時聯係我們: askus@indium.com china@indium.com


Solder Joint Grain Structure

Dross Generation Comparison

Cheers!


Picture: Jim Hevel with Indium Corporation


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焊接含有各種元件大電路板的爐溫曲綫 Reflow Profile for Soldering Thermal Massive Boards

Posted by Anny Zhang on Friday, March 12, 2010

上兩周在一個客戶端那裏, 他對焊接含有各種元件大電路板的爐溫曲綫有點困惑。 

 

通常的爐溫曲綫有兩种:綫性爐溫曲綫(Ramp To Spike---RTS),含有恆溫區的爐溫曲綫(Ramp Soak Spike---RSS).   雖然常規來説,60%-70%不良焊接的根源在於印刷的過程中,但是有時候對爐溫曲綫的微調,也可以大大減少各種焊接的不良現象,提高產率。   

 

在那個客戶端,因爲板子有30cm x 40cm 那麽大,上面有各種常規和不常規大大小小的元件,有些還是十分熱敏感(thermal sensitive)的元件,所以這是一個thermal massive的板子,也就是說板子上各個焊接點同時達到熱平衡(同一個溫度的意思,thermal equilibrium) 比較難。所以我們根據客戶準備使用的合金(當時用SAC 305), 板子的凃層(surface finish/metallization),板子上大概的元件情況,還有回流爐(reflow oven)的區間(當時用10 zones),給客戶設計了一個適合那種產品的回流曲綫(reflow profile)。  這是一個有一小段恆溫區(shoulder soak time)的曲綫,就是在合金到達熔點前(solidus point),來一兩段溫度保持平衡的區間。好在客戶是10個區的回流盧,設計起來條件也比較寬鬆。這樣設計可以大大減少熱不平衡(thermal gradient) 帶來的不良焊接,像unsoldered虛焊,立碑tombstoning, 等。

 

第二天早上,和客戶一起進行了三個不同的檢測后:visual inspection目測, microscope inspection顯微鏡觀測, and X-ray inspection, 一切良好! Yeah Ha!! Cheers!   

 

Pic:   http://mayang.com/textures/Manmade/images/Plastics%20and%20Related/electronic_circuit_board_9131073.JPG

 

 PS:  西雅圖滿街粉紅色和白色的櫻花都很美。 一切安定好后,要開發美國大西北啦! 最近在讀Randy Pausch 的書“The Last Lecture”,這是他回顧人生,面對死亡的一些平淡箴言。 這也有他著名的“Really Achieving Your Childhood Dreams”的錄像,英文的。  

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Pb-Free Bar Solder Dilemma: Price vs. Performance

Posted by Tim Jensen on Monday, January 25, 2010
Many consumer electronics transitioned to Pb-Free 4-5 years ago.  However, there are still a substantial number of electronics being built with Sn/Pb solder.  As some of these products begin to transition to Pb-Free, the decision on a bar solder alloy for the wave soldering process is a challenging one.  There are two widely recognized options to choose from:
  • use SAC305 and keep the alloy the same as the SMT process
  • choose a low silver (Ag)/Ag-free alloy which is substantially lower in cost

From a cost perspective the Ag-Free alloys are 40-50% cheaper than SAC305.  This is a substantial savings when you consider that solder pots hold around 1,000 lbs of solder.  In this arena, Indium offers our Sn995 which is a cobalt doped Sn/Cu alloy.  In addition to being lower in cost, Sn995 produces shinier solder joints than SAC305.

It would be great if that were the whole story, but there are cases when SAC305 should still be considered as a bar solder for wave soldering processes.  One advantage of SAC305 is that it has a faster wetting speed than any of the Ag-Free alternatives.  This can help when you have a board or process that is challenged with poor hole fill.  The chart below shows the difference between popular Pb-Free alloys for wave.

Another potential advantage of SAC305 is in thermal cycling reliability.  Because the typical wave solder joint is large and very robust, reliability may not be a concern for many consumer products.  However, as the reliability requirements increase for industries such as automotive, aerospace, and military, the stronger SAC305 solder joint may be what is needed to meet more stringent reliability requirements.

Both SAC305 and Ag-Free alloys, such as Sn995, have their place within the electronics manufacturing arena, but it is essential that the correct decision is made based on the product being assembled.
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