Indium Corporation
From One Engineer to Another®

Solder Paste and Flux Dip Depth: II

Tuesday, November 15, 2011 by Dr. Andy Mackie [Dr. Andy Mackie]

Following on from our discussions of last time...

As you will recall from the previous post on this topic, My friend and colleague Chris Nash and I were discussing some puzzling results for low dip height found during testing of package-on-package (PoP) materials. The findings will be of interest to everyone who uses a dipping process in both SMT and flip-chip assembly.

Post II:
For greater solder paste and flux dipping heights it appears as though a linear doctor blade (back and forth) used in a dipping process running at high speed will allow dip heights close to those expected from the theoretical engineered limit, for 50 microns and greater dip height. The high speed shear-thins the flux, which has the effect of both reducing the thickness of the boundary layer, and also has the benefit of reducing the extensional (tack) viscosity, so components can be more easily released from the dip tray.

What if you want to go to lower dip depths?

As we move into the area of copper pillar flip-chip dipping, and even (we hear) some Japanese customers doing package-on-package assembly, the dip height (dip depth) can go down to as low as 10-20microns, and this where we are hearing that rotary dip trays are coming into their own. The diagram below shows a simplified version of a flux and solder paste dipping tray.
Rotary dipping tray

Rotary dip trays seem to have the following advantages:

- Height Setting: The dip height/depth is set using two micrometers, so is infinitely adjustable to a precise setting, although the dip height does have to be measured.

- Low Cost: They also add zero capital cost for a new dip depth setting, compared to specially-engineered dipping trays, which can be upwards of $2,000 each.

- Accuracy and Precision of Depth: From a more pragmatic viewpoint, however, the real reason for rotary trays being used with ultra-low dip heights is that the flux depth is actually measured: there is no tacit assumption of a given dip depth being correct and constant, based on the engineering of the dipping tray. As we saw last time, an error of 20 microns is possible, and with a dip height of 50 microns or less, this is a huge problem if you are using a 50 micron dip tray and assuming that you are getting exactly that dip depth.

However, rotary dip trays also have their share of potential problems compared to linear dipping systems: 

 - Larger Surface Area: Flux and solder paste may dry out faster, and a water soluble material will be more vulnerable to the humidity content of the air. It is also more wasteful of flux, since a larger surface area of flux is exposed than will ever be used, although this may also be true of some of the linear tray designs.
 
- Circular Tray: Materials will experience a higher shear rate at the outer edge than in the middle. If spun too fast, dipping materials may accumulate at the edges, thrown outwards by centripetal force.

- Lower Shear Rate: For the same flux or solder paste dip depth, the velocity of the doctor blade will be much lower with a rotary than a linear system. However, as you can see from the illustration below, for a doctor blade moving at 1/4 the speed and 1/4 the dip height, the shear rate is the same.
Shear rate and depth and velocity

As always, please contact me if you need to learn any more.

Cheers!  Andy


Solder Paste and Flux Dip Depth: I

Wednesday, November 9, 2011 by Dr. Andy Mackie [Dr. Andy Mackie]
My friend and colleague Chris Nash and I were recently discussing some puzzling results for low dip height found during testing of package-on-package (PoP) materials. The findings will be of interest to everyone who uses a dipping process in both SMT and flip-chip assembly. Firstly, a little background. Many of you will be familiar with the two types of dipping tray used in both PoP and flip-chip assembly:

Rotary Type - This has a doctor blade that is fixed in place, but adjustable in height, attached to a rotating dip tray of flux or solder paste that spins under the blade, providing a level surface and a known thickness of material into which the component is dipped.

Linear Type - Although the doctor blade in a system of this type is usually the moving component, there are some tools where the dip tray itself moves from side to side under a fixed "blade" or reservoir. EB Datacon flip-chip dipping equipment, for example, may be of either type.

Advantages have been claimed for both types of system, but the rotary type seems to be winning out over the linear type for very precise dip depth control. That said, linear seems to be much more common. Why should this be?

One clue that we recently discovered is that the dip depth for a linear system is always less than the designed depth: whether the fluid in it be a flux or a dipping solder paste. The assumption is that the depth of flux in the linear dip tray is exactly the same as the design height (below).
Ideal dipping

However, as evidenced by both visual inspection of the solder ball / flip-chip bump dip height, and also by direct measurement of the fluid in the dip tray, the actual flux or paste dip height is always less than the design height (below). Why should this be?
Dip Depth 2 - actula situation
The answer can probably be found in reference to the concept of a boundary layer (red circle above): a layer of material immediately adjacent to a surface that is either completely immobile (static boundary layer) or moving at a velocity less than in the bulk of the moving fluid. With no boundary layer, there would be no drag (fluid frictional forces) and of, course, that is why golf balls have dimples: so that the boundary layer is kept mostly beneath the outer surface of the ball, to reduce drag. This principle has also been adopted for some squeegee blades.

The reduction in height is of the order of 10-20microns, as closely as we can tell with the measurement systems available. So, for a 200micron dip depth, this will only lead to an error of -5 or -10% in the actual dip height.

Since most dipping materials are thixotropic, there is the added complication of time dependence of the material's rheology. The fastest way to reach the equilibrium dip depth is to use a very fast movement of the doctor blade system relative to the dipping tray, although this will almost inevitably increase the prevalence of bubbles.

Again, the linear system is most commonly seen for most PoP and flip-chip dipping applications, but it clearly has its limitations, as we will discuss in part II.

I welcome your comments.
Cheers!  Andy

叠成封装(Package-on-Package;PoP) 焊锡膏和助焊剂 (PoP paste and PoP flux)

Monday, February 21, 2011 by Anny Zhang [Anny Zhang]

随着电子元器件组装微型化的趋势(miniaturization),最近有越来越多的客户向我们咨询叠成封装的材料以及相关工艺(Package-on-Package;PoP)

在向客户推荐PoP材料的时候,除非客户已经十分清楚自己要什么,我们一般会和他们详细介绍叠成封装焊锡膏PoP paste 和叠成封装助焊剂PoP flux具体是什么,分析各自的优缺点,然后让客户自己做决定。

Indium 公司的PoP paste (Indium9.88HF) 用的是5号金属粉,金属比重大概在80%-83%之间,根据是有铅还是无铅而定。 我们做过一系列的实验,和常规的SMT 3号粉和4号粉,各种金属比重的焊锡膏做比较,用5号粉在这个金属比重中做出来的PoP paste,各方面的性能最好。 Indium公司的PoP flux (Indium 89HF-LV) 也是根据各种实验结果都是最好的证实后, 才推出的。 通常检测PoP焊接材料, 可以做这三个实验: Transfer Test, Wetting Test, and Electrical Test. 具体的检测方法,Indium公司的Jim Hisert在他的论文中有详细描述。《Next Generation PoP Pastes for Electronics Assembly

PoP Process

一般我个人比较喜欢推荐PoP paste,因为PoP paste能够提供extra solder。 PoP component本来就很薄,在焊接后回流的过程中十分容易“warpage 板翘”,那么component边缘部分就很有可能有一个上下之间很大的gap,导致根本无法形成良好的焊点。但是如果使用优良的PoP paste, paste中的extra solder metal 就能起到一个很好的“粘合剂”作用,即使有warage,也可以有一定的防御。 但是PoP flux在这方面就相对弱一点。

然而,PoP paste中的flux,因为要做很多功夫来清洗powder表面的氧化物,所以在回流过程中会有挺多的outgassing,这就很有可能导致空洞voiding 的产生。PoP flux相对而言,outgassing 就少很多,自然产生voiding的几率也小。

PoP paste and PoP flux

无论如何,优良的PoP paste and PoP flux,在防止wargage和voiding产生的defect方面,都是应该做得不错的。

Cheers!

 

Pic: Indium Corporation

Acknowledge to: Eric Bastow andJim Hisert with Indium Corporation  

Package-on-Package (PoP) Solder Paste

Friday, January 21, 2011 by Dr. Andy Mackie [Dr. Andy Mackie]

A quick trip to discuss roadmapping with one of the world’s top processor manufacturers, and a visit to discuss Pb-free power die-attach materials, left me with a few hours to spare at LAX.

This time around I was trying to work out how much package-on-package (PoP) solder paste we would expect to see for a waferlevel CSP (WL-CSP) or a BGA dipped to half height. The need for some deep thought was driven by a customer who asked at what point a PoP dipping paste needs to go from a type 4 to type 5, 6, 7 and so on (however you define them), based on the PoP/CSP pitch or ball diameter. Good question.

To start with, in order to get consistent quantities of paste on each sphere, the PoP paste metal loading needs to be well below the point at which rheopectic behavior can expect to be seen (that is, much less than 50% by volume of solder powder metal). By doing this, you pretty much guarantee a “monolayer” of solder paste powder particles (radius r) coating the CSP or BGA sphere (radius R). Figure 1 shows the kind of result that is typical for a good paste: in this instance our halogen-free PoP paste Indium 9.88-HF.


Figure 1: 0.4mm CSP dipped in PoP paste
Figure 1: 0.4mm pitch CSP with PoP paste

If the metal loading is too high, even at time zero, you will start seeing large variations in the amount of PoP solder paste adhering to the surface of each sphere (bump), even on adjacent spheres: the small amount of paste that is picked up during the dipping process adheres to the main solder sphere in uneven clumps. This is why standard type 4 printing solder pastes just don’t work in PoP applications: not only is the particle size too big – the rheology is all wrong.

If R>>r, then a reasonable first order approximation is that you can treat the sphere surface as planar and so model the number of solder particles based on a series of hexagonally close-packed particles (Figure 2 gives the definitions).
 
PoP Paste - basis of model
Figure 2: Definitions for the PoP paste dipping process

Using the same model of solder powder particle size as in the discussion on waferbumping paste, you can calculate a couple of potentially useful things:

i/ The maximum number of solder powder particles on each solder sphere (bump)

ii/ The mass of solder paste adhering to each soldersphere

The first (i/) is useful for establishing the inherent variability due to the finite size of the solder powder, and I’m going to suggest another Mackie rule of thumb of a minimum 150 solder powder particles per solder bump, based on the maximum allowed particle size (diameter). The table below gives  the result of this rather simplistic analysis:

Table: Effect of Bump Diameter and Paste Type

Table: Effect of Package Bump Diameter on Solder Paste Type Needed

A 400micron bump should therefore be fine even with a type 3 dipping paste, whereas a 200micron bump will need a type 5 paste.

I look forward to someone proving this wrong. The second (ii/) is helpful, because we can easily use it to test the theoretical mass of PoP dipping paste against what we actually find. Note that this is just simple geometry: it doesn't tell us how much paste is really needed to resolve issues such as the 60 - 90micron bowing we are hearing about from our customers, even with the more rigid PoP packages currently available.

Cheers!  Andy

Epoxy Flux Dipping for CSP and PoP Applications

Friday, January 14, 2011 by Dr. Andy Mackie [Dr. Andy Mackie]

This week a customer in Asia asked why one of our new epoxy fluxes was not allowing the package-on-package (PoP) device to be picked up from the dipping tray. Obviously, the vacuum nozzle must have sufficient force to extract the PoP package from the PoP flux reservoir (yellow, below).
Epoxy Flux Dipping


Those of you who know me also know that I am always trying to reduce things to numbers so, naturally I got thinking about how I would model this from a physical viewpoint and came up with the following:

If the downward force (weight of component plus tack force of epoxy flux) is greater than the upward force (air pressure on the bottom of the component), then the component could not be extracted from the epoxy flux. The figure shows the different variables. Expressing this mathematically, this comes out, in SI units, as:

Downward force = m.g + n.Ft.pi.(d/2)^2

where Ft is the tack force in units of mass per unit area, taken from the maximum tack force determined by the Solder Paste Tack Test from J-STD-005, ANSI/IPC TM 650:2.4.44

Upward force = 101000.A.pi.(D/2)^2

where A is the measure (fraction) of atmospheric pressure and denotes how good the vacuum is (zero vacuum is 0.0atm : hard vacuum is 1.0atm).

There are some uncertainties with this approach: How does the vacuum vary across the nozzle diameter? Does the 5mm diameter probe used in the IPC test equate to a complex CSP (chip-scale package) bottom surface, with many rounded solder bumps or solderspheres? And so on. But, at least the model puts us in the right ballpark. Just to give you a feel for how this works, the second figure shows some results. Note that scenario (iv) is the only one showing problems (negative force balance).

The data implies that you are only likely to see an issue with inability to pick up components from a dipping flux tray if either:

  • Components: Heavy (thick / large)
  • Vacuum Nozzle: Too small a diameter and/or the vacuum is weak/poor
  • Flux: Very tacky (high tack force)

For many of the newer applications, component sphere/bump immersion to just deeper than the bump height (say 100-110%) is desirable. If the customer dips the whole bottom of the component into a standard (non-epoxy) flux, this potentially opens up a lot of issues including reliability (SIR; electrochemical migration); component displacement (skewing) during reflow; as well as difficulty in picking up the component from the tray. The solution to this series of issues, is to choose either a standard flux with a high pre-reflow SIR, such as our PoPflux 30B, or a low-volatile content epoxy flux.

I'll have more to say on epoxy fluxes in a couple of months, as we are currently nearing the end of extensive testing at several customers in Europe and Asia.

Cheers!

Andy

The Printed Circuit Board: More Important Now Than Ever

Sunday, November 21, 2010 by Dr. Ron Lasky [Dr. Ron Lasky]

Folks,

My interest was piqued by a recent article from the pen of good friend, Ray Rasmussen. In this piece, Ray reviews a presentation by Phil Plonski of Prismark Partners on a tear down analysis of an Apple iPad. Ray comments on the profoundly dense interconnection, with package-on-package (PoP), flip-chip, etc. The result is a product with super-dense IC packing with a minimum of printed circuit boards (PCBs) needed. The micrograph, from Prismark, shows this impressive packaging design. 

Ray goes on to lament that these types of designs require fewer and fewer PCBs. He then states: “It won't be long before they learn how to build the iPad and iPhone without a PCB altogether.”

Whoa, slow down! Let’s think this statement through.

The PCB provides at least two fundamental functions:

1.      It provides mechanical support for the electronic components.

2.      It interconnects the components to each other and provides input/output connections so that the electronics can interact with the user.

iPad X section(PCB experts will point out that there are many other functions such as heat transfer, electrical impedance matching, electromagnetic shielding, and a few other things the PCB provides in addition to those mentioned above. Many product designs require all of these functions of the PCB, however, even the most basic designs require 1 and 2.)

It is an imperative in any electrical design to minimize the number of components, PCBs, connectors, etc. in order to minimize cost and increase performance. However, the minimization of PCBs often results in those used becoming more complex and hence having more “value added.”

In looking at the micrograph cross section, one could strongly argue that the PCB has never been so important or so strongly a “partner” in the design. The multilevel, fine feature, high density interconnection provided by this PCB is truly a miracle of modern PCB manufacturing. Any other “PCB-less” design would require these functions and would essentially, by any other name, be a PCB. As an example, let’s say all of these functions were performed by the case of the electronic device. To manufacture this new PCB-less device, the processes that are used to make a PCB would be needed to form these functions in the product’s case.  In addition, solder paste printing, component placement and reflow soldering of the case would likely be a challenge!

So expect the PCB to be alive and well for some time to come…..and never more needed.

Cheers, 

Dr. Ron


Solder Pros Mention Indium PoP Paste

Saturday, December 19, 2009 by Jim Hisert [Jim Hisert]

Two big names in electronics assembly (Vern Solberg and Phil Damberg) recently wrote an article for Circuits Assembly Magazine regarding "PoP Assembly Process Fundamentals".  The article goes through the background of package-on-package, the components, the PoP solder paste dipping process, reflow, and post-assembly solder evaluation.  Most authors would stop there, but as a bonus, Vern and Phil discuss reinforcement, warpage, future trends, and future package technologies.

Now, I like to think I generally have my finger on the pulse of who is using our PoP solder pastes, but this one completely slipped past me.  I was happily surprised to read that they referenced Indium Corporation PoP solder paste - cool!  When I was learning about semiconductor packaging years ago, I learned a lot from Vern's tech papers.  This was personally rewarding to be mentioned by an industry leader like him.  If you're reading this - thanks Vern and Phil!

~Jim Hisert

PoP Clamping Rework Nozzle

Tuesday, December 15, 2009 by Jim Hisert [Jim Hisert]

Click here for a description and video that shows a nozzle design from FINETECH  which clamps down onto PoP components during rework. 

 

The PoP soldering head is an easy-to-use tool for reworking stacked devices as a whole in a single reflow process. It uses vacuum-actuated mechanical clamping tweezers which avoid separating the single layers of a PoP during component removal. The PoP soldering head can be easily adapted to different component thicknesses. Furthermore it is possible to adjust the width of the clamping tweezers prior to the process when the rework arm is swiveled down to avoid affecting other components on the PCB (e.g. accidental shifting of neighboring small passives).”

 

Sounds like this would be great for combating “PoP Quicksand”. That nasty problem that large components have when the vacuum provided by the nozzle isn’t strong enough to lift the package-on-package component back out of the PoP solder paste or dipping flux. Okay, I just made up that term – but it’s pretty descriptive, right?

 

Conceptually it seems to make a lot of sense, please comment if you have any experience with it!

交叉銷售 Cross Selling

Friday, November 6, 2009 by Anny Zhang [Anny Zhang]
PoP Materials

最近,公司在和一個原始設計商(ODM)公司談合作項目。

 

本來的初衷,是希望能給這傢ODM, 它的上游OEM(原始設備製造商)公司,下游EMS(製造加工廠),提供Indium公司性能穩定良好的SMT焊接材料(如錫膏solder paste,錫綫solder wires)等,並為他們提供及時的技術服務和一系列解決方案,協助他們做到最好。

 

但是在相互交流的過程中,我們了解到這傢公司還做IC設計,芯片曡層封裝等(Package on Package; PoP)。其實,在曡層封裝應用中,的Indium 公司也有的很成熟的半導體技術和材料。比如説for BGA/CSPsolder balls, dispensing paste/flux, transfer paste/flux, PoP paste/flux, etc. 

 

站在客戶端的角度,他們也應該希望有供應商能提供這一整套的解決方案,以對内外材料/技術的洞悉,幫助他們順利完成這個(些)大項目。

 

站在我們自己的角度,在協助客戶時,也最好有發現“交叉銷售Cross Selling”機會的眼睛, 发现销售不同产品或向不同部门(或客户)销售的机会,从而帮助客户,满足客户需求,达到销售目的。

 

Cheers!

 

 

PS:  小帆這兩天在博客中寫到“操作系统的改进更新目前来讲都是小步前行。如若想像windows95/98那样革命性的变化,那就要看未来人机交互方式的变化。从某种意义上讲,硬件技术而不是软件技术将是未来变革到来的动力。比如,如果你能把电脑做成手表;如果你的输入设备能凭空展开或投射虚拟。。。”他的話語也讓我立刻想起現在電子行業的微型化(miniaturization),芯片的曡層封裝,3D Dimension, etc. …..  科技以人爲本。很幸運,能生活在高科技的今天,享受各種高科技帶來的服務和便捷!

 

Pic:Jim Hisert with Indium Corporation

Has RoHS Really Been Successful?

Wednesday, September 9, 2009 by Tim Jensen [Tim Jensen]
 In a recent blog entry titled RoHS: 3 Years Later, Dr. Lasky comments on the overall success of the RoHS legislation.  Before implementing the Pb-Free portion of the legislation, companies were extremely concerned about its impact on performance and reliability.  Dr. Lasky reports that there have been relatively few issues.  However, there HAVE been some issues.  I will debate against myself on whether RoHS has been successful or destined for failure. 

Why RoHS is Destined to Fail (aka Against Lasky):
  • Sn Whiskers - Sn whiskers are filament growth that protrudes from pure Sn surface coatings and are a result of the compressive stress inside of that Sn.  For an overview of Sn whiskers, check out the article titled Structure and Kinetics of Sn Whisker Growth on Pb-free Solder Finish.  When looking at Sn whisker mitigation, it turns out that Pb added to Sn is very effective.  That's why Sn/Pb components never show whisker growth.  There are other mitigation techniques such as Ni underplating and doping with Bi but they don't seem as effective a good old Sn/Pb.  Over time (often greater than 5 years), whiskers can grow large enough to form a short between adjacent components.  Whiskers may not be a big issue for cell phones (because of their short life) but is a major concern for military, medical, and aerospace electronics.
  • Pb-Free Alloy Reliability - The two most common alloys used for Pb-Free soldering are SAC305 and SAC387.  When compared to Sn63Pb37, the SAC alloys are considerably more brittle.  This means that under low stress conditions, they actually may be more reliable than Sn/Pb.  However, under higher stress conditions, Sn/Pb can creep to absorb some of that stress while SAC alloys can simply fracture.  The reduced reliability of SAC can be seen under challenging thermal cycling and drop testing.  There are studies on doped SAC alloys that show promise in bridging the reliability gap, but more work is necessary in this area.
  • Higher Reflow Temperatures - The peak reflow temperature for Sn/Pb assemblies was generally around 210-215 C.  For Pb-Free assembly, it tends to be around 240-250 C.  This increase of 30+ C can reap havoc on boards and components.  For components, higher temperatures increase their susceptibility to moisture.  The MSL levels are generally more stringent for Pb-Free.  For boards, you can get barrel cracking, delamination, and CAF growth.
  • Proven Pb-Free Issues: There have been a number of reported issues that are likely related to Pb-Free.  Here are a couple: NASA and Sn whiskers; Pacemakers; X-Box RROD (Red Ring of Death)
RoHS and Pb-Free specifically is simply a ticking time bomb.  Just because there are only a few widely reported issues doesn't mean that nothing will occur in the future.  Anyone who thinks it is successful should be forced to fly only on Pb-Free airplanes.  

Why RoHS is a Success (aka Pro-Lasky):
  • Recycling - As Dr. Lasky notes in his blog, there are a number of benefits to eliminating Pb from the recycling process.  Although, Pb contamination can easily be dealt with at state of the art recycling facilities, there are unfortunately too many uncontrolled reclaim situations in poor and developing countries.  The elimination of Pb makes those people safer.
  • Technology Advancement - Consumer electronics are almost completely Pb-Free and have been since 2006.  Since 2006, we have seen a significant amount of advancement in the technology behind cell phones, laptop computers, and handheld GPS.  Had Pb-Free been such an impediment, there would have clearly been some stagnation in the advancement of those technologies.  In consumer electronics, there has been the implementation of 0.4 and 0.3 mm pitch CSP's, 0201's, package-on-package (PoP) to continue to improve the technologies.  Remember, the first iPhone was Pb-Free!  As the technology advances, there will always be challenges but they are not directly related to going Pb-Free.
  • Whiskers (Non)Issue - It is absolutely proven that pure Sn can form whiskers that could be a long term reliability issue.  However, there are existing Pb-Free alternatives today and in many cases the standard mitigation techniques are good enough.  The real issue here is cost.  People want to use pure Sn (or as little mitigation adders as possible) to get the cheapest component.  However, if you eliminate the Sn, you can eliminate the whiskers.  Texas Instruments uses Ni/Pd/Au for many parts.  That is Pb-Free and contains no Sn.  Whisker free alternatives do exist!
The implementation of RoHS compliance has clearly been successful for consumer electronics.  Those products continue to advance in technology with little issues despite being Pb-Free.  While there are concerns relative to higher reliability assemblies, there are design techniques that exist to overcome those concerns.

Which side of the fence are you on?


Flux Residue Levels: Not as Simple as you Think

Thursday, September 3, 2009 by Dr. Andy Mackie [Dr. Andy Mackie]

After you've reflowed solder in contact with a flux, you're always left with a certain amount of flux residue. There are no clear industry guidelines on how you refer to the residue, and new terminology is emerging all the time. If you leave it up to me, here is what I recommend : 


1/ "No clean" flux residues:

- Standard Residue:  >40%
- Low Residue (LR): Between > 10% to 40%
- Ultralow Residue (ULR): Between >2% to 10%
- Near Zero Residue (NZR): Between 0 to 2%


Each % is given as the weight percent of flux residue after a real reflow process, and refers to the fraction of the raw flux, or flux component of a mixture (such as solder paste or metal-filled epoxy). Note that the exact amount of residue will vary with the reflow profile; the mass of flux or solder paste studied; and the rate of gas flow over the sample material, as well as secondary factors, such as the oxygen level in the reflow atmosphere.

Thermogravimetric analysis (TGA) is a pretty poor method for determining post-reflow residue levels. Results from the use of a platinum TGA sample cup with nitrogen flowing over it have been found in our testing to vary significantly with the mass of sample present, probably because the headspace in the cup acts as a "dead zone" for entrapment of vapor: TGA may therefore give artificially high % residue readings, compared to the results on a flat leadframe or other substrate.

From the viewpoint of a standard semcionductor assembl process, now consider the situation of a low-clearance direct chip attach "flip-chip" or package-on-package application, where the flux is essentially entrapped in a "cage" of I/O's, sandwiched between two flat diffusion barriers. As well as issues of flux residue, this also raises the question of how the electrical properties of the flux will be affected, if more of the solvent and other volatiles from the flux are trapped in the residue.


2/ "Water-soluble" (same principles apply for "Solvent cleanable") flux residues:

- Water-soluble: Residues can be truly dissolved in water to leave a transparent liquid: the color of the this rinse liquid is immaterial,
- Water-dispersible: Non-transparent rinse liquid with any hint of translucency or turbidity


I know that the differences here will be very dependent on rinse-water quality and temperature; chemistry of any cleaning agents; stage of bath-life and so on, but to my mind, if the rinsed liquid is not transparent, then the solids from the flux must be suspended as fine particulates. These particulates usually have refractive indices different from the bulk liquid: the result - turbidity. There may be a means of bath-life end-point determination by turbidity or dynamic light scattering (DLS) or a similar technique; possibly in combination with the standard refractive index measurement that is most commonly used.


In conclusion, note that ULR and NZR fluxes are showing increased usage in flip-chip applications, since these types of material interfere less with the curing of underfill polymers. NZR fluxes are becoming critical for copper-pillar bumping applications.



Just my thoughts - let me know what you think.


Cheers!   Andy

Learn More About PoP Solder Paste

Tuesday, September 1, 2009 by Jim Hisert [Jim Hisert]

From an upcoming SMTAI presentation dealing with PoP solder paste: "...Formulation, particle size, and metal loading are all key factors in the design of a PoP-specific solder paste. The time spent evaluating these new products is well spent. Electrical opens on your boards when using standard SMT materials or outdated dipping pastes can result in costly and time-consuming rework down the road. With the proper material and process, insufficient solder transfer and head in pillow defects can be a thing of the past." 

If you're interested in solder paste, thermal management, or eliminating solder defects - please join us at the 2009 SMTA International Electronics Exhibition this October.  The Indium Crew is scheduled for many presentations, including the Package on Package presentation mentioned above. 

A Model for Component Dipping

Monday, July 20, 2009 by Jim Hisert [Jim Hisert]

Dr. Andy Mackie recently put together a model to determine the probability that a component can be successfully dipped in solder paste or flux.  Here is a little more from him on this subject:

"A customer in Asia was asking why one of our no-clean package-on-package fluxes, the ultralow residue NC510, was not allowing the PoP device to be picked up from the dipping tray. It turned out that the customer was allowing the flux to coat the whole of the bottom of the component, not just the solder bumps, so the vacuum nozzle had insufficient force to extract the PoP package from the flux . I got thinking about how I would model this from a physical viewpoint.

If the downward force (weight of component plus tack of flux) is greater than the upward force (air pressure on the bottom of the component), then the component could not be extracted from the flux. The figure shows the different variables. Expressing this mathematically, this comes out, in SI units, as:

Downward force = m.g + n.Ft.pi.(d/2)^2

where Ft is the tack force in units of mass per unit area, taken from the maximum tack force determined by the Tack Test Method from J-STD-005, ANSI/IPC TM 650:2.4.44

Upward force = 101000.A.pi.(D/2)^2

where A is the measure (fraction) of atmospheric pressure and denotes how good the vacuum is (zero vacuum is 0.0 : hard vacuum is 1.0).

There are some uncertainties with this approach: How does the vacuum vary across the nozzle diameter? Does the 5mm diameter flat IPC probe equate to a much smaller sphere? and so on, but it at least puts us in the right ballpark.
Just to give you a feel for how this works, the second figure shows some data. Note that scenario iv is the only one showing problems (negative force balance).  The data implies that you are only likely to see an issue with inability to pick up PoP components from a dipping PoP flux tray if either:

- Components: Heavy and have many large PoP solder bumps
- Vacuum Nozzle: Too small and the vacuum is weak/poor
- Flux: Very tacky (high tack force)

and certainly, if the customer dips the whole bottom of the component into the flux, this opens up a lot of issues, including reliability (SIR); component displacement during reflow; as well as inability to pick up the component from the tray. This is why we always recommend a flux dipping height of 40-50% of the PoP bump height, to eliminate these issues."

I have found this model not only interesting, but useful for technicians to use when asked why components are 'only dipped 50%'.  As a technician, it is good to have a scientific reason to refer to - even though experience may have already proven the theory to us personally. 

 

 

芯片封装,叠层封装(PoP), 美国西部2009半导体展会

Friday, July 17, 2009 by Anny Zhang [Anny Zhang]
Indium Booth at Semicon West 2009

Indium Booth at Semicon West 2009

芯片封装

芯片封装

这周的7月14号到16号,在美国三藩市(San Francisco) 举行了半导体行业的美国区盛事,Semicon West 2009。 同事们回来分享,总体感觉是各个参展商们都表现得很好。Indium公司一如既往,与大家分享新产品和新科技。在Indium公司提供的各种半导体焊接材料中,前导工序晶圆制造材料(wafer mfg and process),功率半导体封装材料,叠层封装(Package on Package---PoP)材料,是我们展会中的重点。

最近又系统的看了一下,芯片封装的进展,大概分为这几个阶段/方式:一、DIP双列直插式封装。二、PQFP塑料方型扁平式封装和PFP塑料扁平组件式封装。三、PGA插针网格阵列封装。四、BGA球栅阵列封装。五、CSP芯片尺寸封装。六、MCM多芯片模块。

其中近年来热门的叠层封装(Package on Package---PoP),就是有点像盖楼房,搭积木一样,chip里面的die可以叠加在一起,然后chip又可以堆积起来。每次说到这词,我脑海中的第一反应,就是香港那瘦瘦高高窄窄的高楼,密密麻麻;如果做饭炒菜缺盐了,可以伸手出窗户向邻楼借的……

这周在三藩市,同时还有一个太阳能的展会Intersolar. 下次再分享。 Cheers!

Pic: 1. Indium Corporation   2. http://hiphotos.baidu.com/xueyeerr/pic/item/783216d10219aa3e9a502776.jpg

How Much Metal is in Solder Paste?

Monday, June 29, 2009 by Dr. Andy Mackie [Dr. Andy Mackie]

Something that seems counter-intuitive to many customers, yet seems obvious to a rheologist is why the percent metal loading of solder paste varies so much. The most crucial control variables are:

- Alloy type

- Powder size

- Application / usage

I'll tackle the two last points in a later blog entry, but the first point is fairly simple to explain. Assuming that solder powder is formed of identically-sized, unreactive, perfect spheres, the viscosity of the solder paste will depend only on the VOLUME of solder present, and is therefore related to the alloy density. This finding goes straight back to one of Einstein's first papers* where he showed that, for dilute dispersions of identical spheres, the relative viscosity (the measured viscosity of the suspension divided by the viscosity of the carrier fluid), is 2.5 (the so-called 'k' factor or Einstein constant) times the volume fraction. The picture (right) shows the definition of the volume fraction.

As can be readily seen: the metal density of solders can vary from 6.5 to 14.5g/cm3, and changing the metal density therefore necessitates adjusting the metal weight percent accordingly. This also varies with the usage:

 1/ For printable paste: a 6%w/w spread is possible

 2/ For package-on-package paste: over 10%w/w spread in metal loading may be needed

For both 1/ and 2/, of course, the goal is to maintain the SAME volume fraction, so the rheology of the solder paste remains the same.

Simple algebra will allow you to derive an equation so you can plug in any density of alloy for a solder paste and calculate the required weight percent of that metal. I can email you the solution if you're stuck, just click on the "Contact Me" button (left).

Also note that changing the flux will not only change the density (flux densities can range from 0.85 - 1.05g/cm3), but will also change the rheological properties of the paste significantly. Quick plug: Ron Lasky was good enough to give me a chance to discuss solder paste rheology a few weeks back, and there will be more about this topic in the coming months.

Cheers!  Andy

* A. Einstein, "Concerning the motion of particles in quiescent liquids as required by the molecular- kinetic theory of heat," Ann. Phys., i_7549-560 (1905)

Indium公司李宁成博士专访(Dr. Ning-Cheng Lee)

Tuesday, June 23, 2009 by Anny Zhang [Anny Zhang]
李宁成博士Dr. Ning-Cheng Lee

李宁成博士Dr. Ning-Cheng Lee

今天,有幸约到公司的在行业中的全球活招牌---李宁成博士(Dr. Ning-Cheng Lee)---吃个便饭,请教了他对行业动向的一些看法。

109SMT行业的大趋势?

李:(笑"你这个topic很大噢")主要还是component方面的变化,从2D package 转向 3D package,像盖楼房一样。以前die小,package大;那就在package上下功夫。现在已经是CSP(chip scale package)了,package已经缩小到和die一样了,无法再缩了,那么要继续微型化,就只能3D了,也只有这样可以有更好更快的电子产品。所以PoP (package on package,叠层封装) and 3D die stacking会越来越流行。 

2.基于这个大趋势,SMT行业技术方面的动向,以及其带来的挑战?

李:目前die stacking 主要涉及的是memory die, 因此还没有对散热问题带来挑战。但是以后的micro-processer,除了减小尺寸来增加transistor的个数, 另外一个途径就是stack the die 从而达到微型化的(miniaturization)  叠了45层,micro-processer的个数增加了,功率增加了,散热和可靠性是一个主要的挑战。 

3最近有许多文章都在讨论SMT工厂兼做太阳能光伏组装(Solar Cell Assembling的后道工序。您是如何看待的?这会有什么挑战吗?

李:目前应该不会有什么大的挑战。需要解决的技术问题, SMT行业和半导体(Semiconductor)方面,有很多经验/技术是相似的;半导体行业的许多经验,以前都已经转用到SMT行业了。类似的,太阳能光伏组装也可以借鉴这些SMT的经验。这可以协助太阳能行业更好地做到low cost的流程,从而达到grid parity(太阳能电网性价比)。不过至今,似乎还没有SMT厂商在做太阳能光伏组装。我们还是拭目以待吧。

 

PS: 哈哈,这顿饭除了有一如既往的"听君一席话,胜读十年书"之感,还真的是免费午餐哦。"家事国事天下事,事事关心";目光炯据,思想深邃的李博士,常常在我叽叽喳喳地说完一些社会现象和个人看法后,能一语中的地指出其本质或是深层次的含义。俗话说"小人谈人,中人谈事,高人谈哲学";我是小人或中人,谈人又谈事;李博士是高人,能一针见血地指出其中的内涵。看来姜还是老的辣!感谢李博士!

Pic: Indium Corporation

Everyone Makes Mistakes

Wednesday, June 10, 2009 by Jim Hisert [Jim Hisert]

This is something you may have run into if you’ve ever manually dipped and placed PoP components.  Yesterday while trying to hold a conversation about the package-on-package process, I lost track of the very same process I was discussing.  I neglected to dip one of the components into solder paste before placing it on the board.  This is a picture of what happens.  The stack itself soldered well, as would be expected, but fell off when the board was lifted from the conveyor at the end of the line. 

 

If you’re wondering what a small error like this costs:

1 hour lost time + price of the board and components.

 

Luckily the other 14 PoP stacks can still be used for cross-sectioning and learning more about the PoP paste that was being evaluated.  If this was a production board I would be able to simply dip the stack and re-place it on the pads, send it through a second reflow, and test the final assembly for functionality – but you just can’t get away with that during evaluation.

 

8 Reasons Why You Need To Re-evaluate PoP Pastes

Friday, May 22, 2009 by Jim Hisert [Jim Hisert]

A lot has changed in the world of package-on-package in the last few years.  The most obvious change that I have seen is the development of specialized pastes for component dipping.  If you haven’t tried one of these pastes, here are 8 reasons why you should:

 

8)       More consistent transfer over time

7)       Head-in-pillow elimination

6)       Better wetting to a range of alloys

5)       Optimized metal loading

4)       Specially designed powder distribution

3)       Halogen-free flux formulations

2)       Maximized transfer volumes

1)       Higher possible yields

A New Blog - Françoise in 3D

Thursday, February 5, 2009 by Jim Hisert [Jim Hisert]
Franoise Queen of 3D甔 von Trapp at last years Device Packaging Conference

Franoise Queen of 3D甔 von Trapp at last years Device Packaging Conference

I love exciting blogs, they are a change of pace in our industry.  Here's a new one that you should check out: Françoise in 3D.  It offers a growing base of knowledge that is geared towards the evolving field of 3D IC packaging innovation.  I'm not sure where the topic boundaries are set, but I hope we will see some entries regarding package-on-package (PoP) assembly or design.

 

Good luck Françoise, we look forward to your foresight in this 3 dimensional world!

 

Buying a Mitsubishi Evo X

Wednesday, January 28, 2009 by Jim Hisert [Jim Hisert]

Have you ever had a hard time getting help with something?  For the last year I’ve been searching for a new vehicle, which can be a long journey for a technically oriented car guy.  The problem has been that the local dealerships in my region are unwilling to take their customers seriously.  The exact car that I was interested in sits only 13 miles from where I live, in a showroom.  The salesman who asked me if I needed anything (notice I didn’t say “helped me”) admitted that he didn’t know anything about the car, and that he didn’t want to – since it was to be shipped to somewhere where it would sell.  He then mentioned that my Jeep Wrangler couldn’t be traded in because it was a gas hog and there isn’t a market for those in central NY.  I left disappointed, did I mention I was asked not to sit in the car or open the hood?

 

The next stop was a dealership 60 miles away.  This dealership would not allow anyone to test drive the Lancer Evolution X.  This time I was allowed to at least sit in the car, check out the engine, trunk, and other components.  Still, no test drive = no sale.

 

I was done wasting time with salesmen that had no interest selling their performance car.  These guys just wanted to sell economy cars all day.  Easy, but what fun is that?  A dealership 100 miles away told me over the phone to stop by and try out the car.  A test drive is all I needed, and I left the dealership with a new car that day.

 

Why does this relate to us?  I don’t expect you to make big decisions about ball attach fluxes, flip chip fluxes, package-on-package pastes, or bumping materials without feeling confident you are getting the right product for your application.  Sure, a car isn’t a consumable item like flux or solder – but I understand that you need to spec in the materials that you use and it can be a pain to change.  Let’s get it right the first time!

 

~Jim