Metallization Paste

Maria Durham, Indium’s new Technical Specialist in Semiconductor and Advanced Assembly Materials, has been doing some research on indium lead (In/Pb) solder alloys. We chatted about her findings this week. 

 [Andy C. Mackie: ACM] Which indium/lead solder alloys are most common, and what are their properties?

[Maria Durham: MD] Firstly, the use of lead-(Pb-)containing solders in some soldering applications is restricted due to local environmental and RoHS compliance, but there are still many applications where they are  allowed. Many military, aerospace, and industrial equipment uses, as well as many applications related to vehicles, are exempt. The table below shows the most common indium/lead (In/Pb) alloys (pink) and their properties, sorted by liquidus temperature; the higher of the two melting points (solidus and liquidus) seen for non-eutectic alloys. In blue are three comparison materials.

Indalloy 205 is the most commonly used, probably because it has the closest liquidus temperature to the tin/lead eutectic (183°C), 63Sn/37Pb (Indalloy 106). This means it can be reflowed using a standard Sn/Pb eutectic profile. The next most common alloys that are used are Indalloy7, 204, and 206.  Besides the melting range, indium has comparable thermal and electrical conductivity to standard materials.

[ACM] What makes indium-lead (In/Pb) solders so attractive, and why have we seen a recent resurgence in their usage?

 [MD] One main attraction to using indium/lead (In/Pb) solder alloys in soldering to precious metal surfaces is that, unlike tin-containing solders, they do not leach gold. That is, gold does not dissolve in them to any appreciable extent. During discussions at Semicon West in 2011, one of our California customers reported going through 8 simulated reflows with Indalloy 205 in contact with a gold surface with no loss of joint strength and no joint embrittlement. That is pretty impressive. Note that embrittlement is often caused by gold-intermetallic formation. It has been noted that even at 250°C, 50In/50Pb dissolves Au at a rate 13 times slower than it does into 63Sn/37Pb, although this, of course, is a kinetic, not a solubility limit, study.

The higher melting Indalloy 164 (92.5Pb/5In/2.5Ag) has the lowest coefficient of thermal expansion (CTE) of all of the In/Pb solders and is able to withstand the higher temperature excursions that can be seen in step-soldering type applications (where a very high melting solder is used to form the first joint, followed by a next lowest melting alloy, and so on). This is seen in applications such as power electronics assembly, where the first step solder is often used for die-attach either as a solder paste, wire, or preform. The high melting point helps the solder withstand the operational temperatures associated with under-the-hood electronics, in applications such as engine control modules, where Indalloy 151 (92.5Pb/5Sn/2.5Ag) or Indalloy 163 (95.5Pb/2Sn/2.5Ag) are most commonly used. In/Pb solder is excellent on very rigid structures such as ceramic-to-metal or ceramic-to-ceramic. The desired solidus / liquidus temperature range can be adjusted by changing the indium:lead ratio, making it very easy to “dial in” the alloy to a specific reflow process.

Another attraction to using In/Pb solders is that they exhibit good fatigue resistance in thermal cycling from -55°C to 125°C.  In testing, the 50In50Pb solder joint fatigue life is about 100 times greater than that for 63Sn/37Pb.

 [ACM] What fluxes are used in these applications, and how are they formulated differently?

 [MD] The fluxes most compatible with the lower melting point (<200°C) indium-containing solders are NC-SMQ-80 (solder paste) or the lower-tack TacFlux® 012 (suitable for use with wire, preforms, and spheres). These are no-clean fluxes, specifically formulated for lower temperature reflow.  Under appropriate low temperature reflow these fluxes leave behind benign residues that do not need to be cleaned off (“no-clean” flux), although they are often cleaned off in most practical applications, usually to ensure reliable wirebonds absent of flux spatter.

 To learn more, please contact us.

 Cheers!  Andy

Musings on Metals: Copper

It could be argued that civilization began with the smelting of copper.  Although thousands of years before, humans fired clay to make figurines and containers, smelting required several non-obvious steps.  After all, the firing of clay, at some level, can be accomplished by simply dropping clay into a fire.

To smelt copper, our ancestors had to:

1. Take malachite (see photo) or another copper ore, grind it up or break it into small pieces
2. Mix the ground malachite with carbon
3. Heat the mixture in a vessel to 1,085^oC. 

Malachite Ore

Achieving this temperature with a wood fire is, to me, astounding.  Think about those days when you are grilling some burgers.  You leave the grill on after the burgers are done, to burn off the grease.  You come back 20 minutes later and the grill is at 500^oF.  You can feel the heat.  Even touching the knob to turn the gas off is intimidating, as the heat drives you back.  This temperature, 500^oF, is only 260^oC!  The ancients reaching 1,085^oC with wood and bellows is, indeed, impressive. By the way, a good rule of thumb to convert degrees C to degrees F from 100^oC to 1,500⁰C is that 2XC=F, this fast approximation is accurate to about 10% in this range.

The confluence of the three procedures is not only non-intuitive, but think how many times the smelter of old could only reach 900^oC and failed.  I have argued that if copper melted at 1,200^oC or so, civilization would have never gotten started.  This temperature is perhaps a little too high to reach with a wood fire.  The smelting of copper encouraged investigations into other metals, eventually resulting in the discovery of the processing of iron, an even less intuitive process than smelting copper.  So, I believe that the success with copper was necessary to the production of steel. 

Copper smelting became an industry that encouraged permanent settlements and stimulated trade, which encouraged writing and ciphering.  An effective copper smelter would likely keep secret some of his craft as he wanted a competitive advantage.  He could make more by smelting copper than doing anything else, so he almost certainly was an early specialist.

Considering all of this, I believe that without the discovery of copper smelting, we might still be living in huts or teepees, using stone tools, and living a nomadic existence without commerce, writing, or mathematics.  Examples to support this thesis are the state of native peoples in the Americas in the 1400s.  These native peoples had never learned to smelt metals and hence also lacked the follow-on aspects of civilization mentioned above.

Today, copper is a foundation material for electronics, given its excellent electrical conductivity, second only to silver.  Copper’s ductility likely aids in the formation of PWB traces and plated through-holes in that it resists cracking.

Additionally, copper's ability to form an electrical and mechanical bond with solder is another trait that makes it a winner as an electrically-conductive assembly material in modern electronics.

Copper has been used for more than 10 millennia, but, as with most metals, 90 to 95% of it has been mined since 1900.  About 15,000,000 metric tons (MT) are used each year, third to aluminum’s   22,000,000 MT and steel’s unequaled 1,000,000,000 MT.

In the next installment, we will discuss tin and how it forms an intermetallic with copper during soldering.  Thus making solder paste, solder wire, and solder preforms critical components of electronics assembly.

 Cheers,

Dr. Ron

Folks,

Patty is getting ready for her meeting on "Copy Exactly" with Mike Madigan.......

It was after 6:30 PM and Patty was just arriving home.  Since Patty was working late, Rob had agreed to make his signature dish, crispy macaroni and cheese.  Patty and Pete had just finished their project to develop a copy exactly strategy for ACME.  They would present it tomorrow to CEO Mike Madigan.  The local GM, Sam Watkins, would be there too.  Technically Mike was her boss in her Senior VP position, but since she had an office at the ACME facility in Exeter, NH, she reported to Sam - “dotted line.”  Patty had been working late for weeks on this project and was glad that the greatest portion of the work was over.

As she opened the door to her house, her twin 2 year old boys ran up to her in their excitement to see their mom and nearly knocked her over.  She tussled with them for a few minutes and then went to give Rob a hug.  He had the dinner on the table and they all quickly sat down.  Rob and Patty had a "no technology" rule at meals…..no mobile phones, iPads etc.  Meal time was family time.  After discussing the events of the day, Rob’s face lit up.

“I found out today that there is something we look at more than anything else,” Rob stated.

“OK, OK, let me guess,” Patty replied.

After a number of tries, she hadn’t gotten it.

Alright, I give up, Patty said with playful exasperation.

“Indium, or really Indium Tin Oxide (ITO), it is a transparent conductor of electricity.  We look through it when we look at our computer, tablet or mobile phone screens.  Think about it, for most of us we probably look through ITO for 8 to 10 hours a day.  It’s like we have a love affair with the stuff,” Rob explained.

Patty almost choked on some of the mac and cheese on the last comment.

“Why have you become such an expert on this stuff?” Patty asked.

“Well, you remember that ACME may go into component assembly? Sam asked me to look into indium thermal interface material (TIM)  for some of the component packages that need to dissipate a lot of heat,” Rob answered.

Patty knew a little bit about TIMs, but not about ITO.

“But why did you learn about ITO?” she asked.

“Sam is worried that Indium supplies may not be enough to satisfy TIM requirements, so he asked me to look into it,” Rob answered.

“What is the conclusion? Patty asked.

“Well, Indium is about as common in the earth’s crust as silver, but a little more difficult to extract.  This probably gives it the reputation of being rare.  Fortunately for me a recent analysis was performed that showed that the indium supply will be more than adequate for the next 75 years ,” Rob said.

Rob went on, “Indium is a very interesting material, it is one of the few materials that wets glass, so it enables metal sealing to glass.  It was only discovered in 1863 and it wasn’t until the 1930s that the first practical use for indium was discovered: aircraft bearing lubrication.  In a sense, it could be argued that it is one of the materials of the future, as we are just now learning about its potential.”

While he was talking, Rob reached into his backpack and took something out.

“Look at this, or rather listen,” Rob said.

With that, he took a thin bar of metal and bent it. A crackling sound came from the metal.  Patty was fascinated.

“What was that?" she asked.

“When a thin bar of indium is bent, it gives off a sound.  It is called “Indium Cry.”  The salesman for the TIMs we are using let me borrow it for a presentation I am giving to Sam Watkins next week,” Rob answered.

Dinner was soon finished and Patty had to get the boys to bed after playing with them for awhile.  Today was Spanish day and all of their discussions were in that language.  Another day was Mandarin Chinese day.  The boys already understood the three languages spoken at home.

A few hours later, Patty lay in bed - energized by the thought of her meeting tomorrow.

When she woke up the next day, she exercised at home, ate breakfast, and took the boys to day care.  See arrived at the office 30 minutes before the big meeting.  After checking emails, she went to the conference room where the meeting would be held, to set up her computer.  At precisely 8AM, Mike Madigan and Sam Watkins arrived.

“OK Coleman, let’s get this show on the road,” Madigan commanded.

“Since our last meeting we have analyzed assembly equipment and materials to determine which ones would be best for a copy exactly strategy,” Patty began.

She then showed her third slide and spoke to it.

“The winner for component placement equipment is Optoplace, as are their stencil printer and reflow ovens.  Exactotest makes the winning testers and ElectoMaterials the best solder paste and solder preforms,” Patty went on.

“Can you explain your methodology?” Sam asked.

“We looked at what The Professor calls ‘Profit Potential,’ simply the equipment and material that gives the most profit, assuming you are running a well tuned organization.  Fortunately, since ACME has 80 assembly lines we were able to get real process performance data on all of the major machines available, ” Patty answered.

“You answer seems a little evasive, why didn’t you use ‘Cost of Ownership?’” Madigan challenged.

“Some machines cost less to own, but they are down more for assists and when they need repair, we have to wait longer for the repair man.  From what The Professor taught us, uptime is very important. Anything that hurts uptime, like a late repairman or a machine that needs more assist time, will hurt profits.  The same is true for materials like solder paste.  If they cost less, but result in line downtime for response to pause issues or some other fault, they hurt profitability.” Patty responded.

Just then Sam’s administrative assistant, Clare Perkins opened the door.

“As you requested Mr. Madigan, your guest is joining the meeting,” Clare said.

“Well Torant, looks like Coleman said you lost,” Madigan said to the new arrival.

Upon seeing Rex Torant, Patty became a little unsettled and Pete turned his famous crimson red.  Patty and Pete called him “Rex the Torrent” as he spoke so rapidly when trying to sell them something.  Both found this manufacturer’s “rep” annoying.

“Everyone, I invited Rex to the meeting.  We met at the airport last night and started chatting.  He assured me that his Pinnacle equipment line and Ultima solder paste would be the winners today since they have the lowest cost of ownership,” Madigan explained.

Torant saw the slide announce Optoplace, Exactotest and ElectoMaterials as the winners.

“My products are just as reliable and cost 30% a year less to own,” Torant fumed at Patty.

Patty had not anticipated Torant’s attendance at the meeting but had prepared for this type of question.

“Mr. Torant is correct, however Pinnacle’s component placement machines have more downtime for machine assists and, when the equipment does malfunction, it is down for repairs on average for 28 hrs, whereas Optoplace is only down for 14 hrs.  All in all, Optoplace machines are up 6 hrs more a week in a two shift operation,” Patty calmly responded.

Will Patty’s arguments win the day?  Can a 30% more expensive machine really have more “Profit Potential?”  And what about the solder paste and materials?  Stay tuned.

Cheers,

Dr. Ron

image

No one likes being controlled by the cost of silver. We deal with fluctuating Ag costs here at Indium Corporation on a very large scale – so I understand the issues with using Ag-filled low temperature metallization paste for thin-film solar cell interconnection.

People always ask for alternative fillers like copper – although the chemistry of metallization paste doesn’t allow the substitution of most filler materials. Our solution is a new material: silver-plated copper particles.

Silver-plated copper particles allow us to utilize a very low amount of silver precisely where it needs to be, on the surface of the particles. By tricking our metallization paste chemistry into thinking it is still working with silver flakes, we are able to maintain the same high levels of flexibility, fine line printing, and adhesion that we have become accustom to with materials such as LT-918 metallization paste.

Due to the inherent bulk conductivity difference between copper and silver, very lowest resistances will still be achieved with solid silver flake metallization pastes. The silver-plated copper material has performed unexpectedly well in electrical performance though, winning over some customers due to a substantial difference in price.

Our new silver-plated copper particle material is currently in beta testing, and has completed over 2,000 hours of dry and damp heat testing. Our data so far has confirmed superior print performance, and customers like the fact that the material can be shipped at room temperature. If you are interested in beta testing the material, please let me know.

~Jim

We are frequently asked if it is possible to solder to aluminum. The answer is yes, if the following guidelines are followed: 

FLUXES:
Because it is difficult to solder to aluminum, Indium Corporation developed Indalloy Flux #3 (activation temperature is 96-343°C) to remove the tenacious oxides that prevent the solder from wetting to the surface. This flux is very corrosive and is not recommended for electronic applications because, if any of the post-reflow flux residue remains after a warm water rinse with mechanical scrubbing, the joint may be compromised. This flux is recommended for mechanical assembly joining applications only. 

Another alternate solution is to use a forming gas consisting of nitrogen and hydrogen. This method of oxide removal is generally used when the soldering temperature is greater than 350°C which is ideal for activating the hydrogen to reduce the oxides. With this method, there is no post-reflow flux residue to clean up.

METALLIZATIONS:
An alternate to corrosive fluxes is to nickel plate the aluminum so a weaker flux (RA, ROL1) can be used. These fluxes are less corrosive and can be easily removed with an appropriate solvent.   There are many solder alloys that will wet to nickel. Check out our solder alloy physical properties table.

SOLDER ALLOYS:
The solders that are normally recommended for joining aluminum are:

• Indalloy #201 (91Sn, 9Zn); 199°C E
• Indalloy #176 (95Zn, 5Al); 382°C E. 

Here is a question that was posted and answered on our website back in 2006, I think it is still quite relevant:

Question: “Why does your Application Note for cleaning of indium ribbon for thermal interface recommend a mild (5-10%) HCl acid solution, yet [the] MSDS for Indalloy #4 (100%) says to avoid contact with acid? My past indirect experience with indium usage indicated some cleaning procedure of the oxides was necessary to achieve good thermal contact resistance.”

Answer: “Thanks for contacting the Indium Corporation with your request. If the indium ribbon is stored and handled (stored unopened in an argon or nitrogen pack – placed in a dry box) properly and it solders well in your process, this procedure should not be necessary. When following this procedure, the HCl solution should be applied to the indium metal to clean it thoroughly, and then dried with nitrogen.”

If you want to know more about metal thermal interface materials (TIMs) (handling, preparation, or process parameters), send an email to our global technical team at: askus@indium.com. They are ready to answer your question!

~Jim

Recently I was testing the resistance of a new low temperature metallization paste* (for solar photovoltaic assembly) in the lab. The samples were initially tested with a 4-point probe, just before entering a chamber set at 85°C and 85% relative humidity. To my surprise, the resistance dropped noticeably (as seen in the chart).

I brought the results to the material’s creator in our R&D department, ready to wow him with my discovery. I exclaimed, “I just finished testing the samples we put into the 85/85 chamber and can’t believe the values I’m getting!” Without a flinch he replied: “The resistance went down, didn’t it? That’s a unique feature of this material.”

While I didn’t gain any cool points in R&D for discovering an awesome new feature of an upcoming product, I hope the trait of this material can be useful for our customers (some of whom have since noted the improved characteristics after reliability testing).

The thing I learned from this experience is how important end of life testing is for metallization paste – all too often samples are only compared based on time-zero testing. This will change the way I compare metallization pastes from now on.

~Jim

*For my followers who aren't familiar with low-temperature metallization paste,it is also referred to as "grid ink", "silver ink", and "conductive ink". Low-temperature metallization paste is a silver-filled contact material used in the assembly of photovoltaic solar cells. It gets its low-temperature label because it is processed at lower-than-traditional glass frit temperatures of ~1,000°C. In addition to its role as a contact for thin-film connections, low-temperature metallization paste is also useful as a low-temperature alternative metallization on Si-based cells.

Learn more here.

Anyone who has used wave soldering to assemble PCBs knows about that chunky layer of metal that collects on the smooth surface of the molten solder. This is solder dross; it is composed of oxidized metals and impurities that collect as the molten solder contacts the air and manufacturing environment. This happens regardless of alloy and is a normal part of the process, often consuming up to 50% of the bar solder added to the solder pot. In the past, this dross was collected as waste and disposed of, but solder dross is more than 90% valuable metal. This value should be recovered.

Nowadays, typically, this dross is collected and returned to a metals supplier for recycling. Indium Corporation now offers two programs for recycling solder dross. The first program involves simply sending back dross waste in return for a portion of the metal value as a credit. The second option involves sending back dross, which is converted to bar solder (within the original spec) and returned, with you paying only a fee for processing. When dross arrives, regardless of which program is chosen, it is electrolytically refined and the pure metals are recovered and converted back into usable bar solder. Often, this reclaimed/recycled metal has a better purity than virgin metal.

Dross is not the only form of solder that can be recycled. For instance, when changing to a different alloy in a wave soldering process, the entire solder pot will need to be emptied. The old alloy can be collected and recycled, lowering the amount of capital necessary to switch alloys. Bar solder and wire that have not been used within the shelf life can also be recycled to get back some of their value.

Contact me if you want to discuss this.

Folks,

Rob heads to Guadalajara to solve the QFN voiding problem......

As Rob sat on the airplane, he was excited to go to GDL (Guadalajara, Mexico) to help solve the voiding problem. He knew Patty would be a little peeved that he asked for Pete to come along, but she was gracious, recognizing that Rob would benefit from a success in this effort.

As the plane circled for a landing, Rob was preparing for the somewhat comical trip through customs. He always thought that the red light/green light method of determining if they were going to search you bags was unusual. Oh well, go with the flow.

The ride from the airport was about 40 kilometers to the factory through GDL’s bustling traffic. After arriving at the plant Rob was relieved to see that Miguel Mendoza was there to meet him and Pete. Rob had worked with Miguel in the past and respected him as a process engineer. Miguel told them that a kick-off meeting was scheduled with the site GM, a fellow from the US named Grant Wilson.

As the meeting started, Rob introduced himself to Wilson in Spanish.

“Wow,” Wilson chuckled, “when asked if I am bilingual, trilingual or American, I have to say I am American.” “But, I am taking Spanish lessons,” he continued.

Rob looked at Miguel and saw him roll his eyes. But Rob thought it was at least a nice gesture that Wilson was taking Spanish lessons.

“Perhaps someone could share what actions have been taken and what the status is,” Rob suggested.

“Miguel, could you give Rob an overview of where we are” Wilson asked.

Miguel began, “The warranty send back rate is 5% on Druid phones. Almost all of these failures have been traced to high powered QFNs that have significant voiding under the thermal pad. The voiding percentage is about 50-70%. About a week ago we obtained Derrick Herron, Dr Yan Liu and Dr Ning-Cheng Lee’s recent paper, Voiding Control at QFN Assembly, at SMTAI 2011.  We changed our stencil design, as suggested in the paper, to allow for venting of the solder paste volatiles and voiding went down to 30 to 50%.”

“What level of voiding would be acceptable?” Rob asked.

“We’re not sure,” Miguel answered.

“So it seems we have two issues, one is to determine if 30 to 50% voiding is OK and the other is to see if we can reduce it further,” Grant Wilson reasonably commented.

“My sense is that we need to be in the less than 30% range,” Rob added. “This may require that we use solder preforms. Voiding is caused by outgassing but also by insufficient solder,” Rob finished.

“OK, you two go and solve the problem and get back to me. You have 3 days,” Wilson commanded.

Rob, Pete, and Miguel headed off to get started on their assignment. Rob was really glad Pete was there.  He was an expert in setting up and optimizing the component placement machines that were at this site.  Fortunately, Rob had also brought some solder preforms with him, expecting that they would be required. A call to the QFN vendor confirmed that less than 30% voiding should be the target. Rob looked at the data and x-ray images of the work that Miguel and his team did to reduce the voiding by improving the venting of the flux volatiles. He was impressed. But he didn’t think it would be enough.

(Dialogue translated from Spanish)

“Miguel, I’m almost certain that we will need to use solder preforms on the two most critical QFNs,” Rob began. “There are two major reasons for voiding, the first is flux volatiles forming voids, the second is solder starvation. Most people don’t realize that solder paste is only 50% by volume metal. In cases like this, where we really need low voiding, often the only path to success is to use solder preforms to add solder metal,” he finished.

Rob then showed Miguel Seth Homer’s SMTAI 2011 paper Minimizing Voiding in QFN Packages Using Solder Preforms. This paper describes the process steps needed to achieve a successful QFN solder preform process. Rob and Miguel spent the better part of a day setting up one assembly line to assemble with the solder preforms using this paper as a guide. They assembled 100 phones and the voiding level was 10.5%.

Early the next morning, they met with Grant Wilson.

“By the smiles on both of your faces, I gather you were successful?” Wilson asked.

Rob went on to explain how they determined that solder preforms were needed. He explained the process and waited for questions.

“What do solder preforms cost?” Grant asked.

“They are about $0.02 (US) in quantity, but understand that your warranty cost per $200 phone is at least $10 right now (0.05x200),” Rob answered.

“Did you have to slow the process done?” Wilson asked. “I have been a fan of the work that you and Patty Coleman have done with The Professor, you have convinced me of the importance of throughput,” he finished.

“The Professor has pointed out that almost never is a line completely balanced. Your flexible placers were waiting four seconds for the chip shooters. We put the preforms on the flexible placer and tuned up both machines by optimizing the feeder placement. The cycle time is now 1.25 seconds faster for the 3 phone per PCB card,” Rob answered.

“I’m curious, what was the greatest challenge?” Grant asked.

“Rob pointed out that the correct placement of the preform on the solder paste deposit for the heat sink part of the QFN is critical. We needed to assure that the preform was pushed into the paste far enough to leave a ring of paste around the preform to assure good mating with the QFN.  We couldn't have done this without Pete, he really knows the placement machines,” Miguel answered.

Miguel then showed Wilson an image from Seth Homer’s paper that displays this situation .

“Guys thanks for the great work. I have to admit that I didn’t really know anything about solder preforms, before today. In certain cases it is obvious that they can be lifesavers!” Grant summed up the situation.

“To celebrate your success, I’m treating for dinner tonight at the Santo Coyote, let’s meet there at 7PM,” Wilson suggested.

“Thanks,” Rob, Pete, and Miguel said in unison.

Santo Coyote was Rob’s favorite restaurant in Guadalajara, but it was Patty’s too. Rob was a little sad she couldn’t join them.

 Epilogue: Three months later it was confirmed that warranty send back rate was approaching zero.  Miguel was promoted to senior engineer for his part in the solution to this costly problem.

Cheers,

Dr. Ron

Solder powder particle size and shape impacts the functionality of solder paste in many ways: printing/dispensing/dipping; solderballing; graping; voiding; tack and so on.

For this reason, I just spent an interesting couple of months leading a cross-industry (two solder paste suppliers and two solder paste users) group to help my old friend Brian Toleno, chair of the IPC 5-24b (Solder Paste Task Group) put the finishing touches to the final version of the J-STD-005A. The concerns were with the definitions of powder size in paste: both the distribution and the “maximum allowable particle size”. We reached a nice pan-industry consensus, which should allow the J-STD-005A to see the light of day as a published document in 2012. I also saw some recent work by colleagues on the effect of particle size on surface area. I didn’t see the derivation of this work, so I want to show you how to calculate the surface area of solder powder in a paste.

Assume solder paste at a weight loading of x%. [Note that: As the solder powder size (diameter) decreases, the metal loading is usually also decreased by 0.5% or more to compensate for the boundary layer of thixotropic flux adhering to the particle surface, but let's make the first order assumption that x is independent of particle size]. So 1 gram of solder paste contains (x/100) grams of solder metal.

If the metal has a density of r (rho), then the volume of metal (v) per gram of solder paste:

               v = x / (r * 100)

Let’s assume that the metal particles are monodispersed (i.e.: all the same diameter (d)), so the number of particles per gram of paste (n) is then simply v (total volume of metal per gram) divided by the volume of one particle (v_p).

               n = v / v_p = x / (r * 100 * (4/3) * pi * (d/2)³ )

We can now also calculate the solder powder surface area (s) per gram of paste from our knowledge of n and the surface area per solder powder particle (s_p):

               s = n * s_p = n *4 * pi * (d/2)²

It is a simple matter of algebra to show that the ratio of surface area to volume is merely an inverse of the particle radius or diameter (I’ll leave that as homework for you):

A while back, I did a little Excel numerical integration to show the effect of powder type on the population distribution, and hence how powder “type” (2,3,4,5 and so on) affects the surface area, with some assumptions thrown in about the width of the distribution. The results are shown below, and are pretty much as you would expect. As you go from type 3 to type 6, you see about a 10 fold increase in the surface area.

前段时间有个客户说Indium3.2的印刷性能很不好，锡膏在印刷时的滚动不行，而且还堵塞网孔。Indium3.2是一款水洗性的无铅锡膏。

我们详细问了客户一系列问题后，发现客户用的这款产品SAC305, Type4 powder，金属比重居然有89.5%。根据我们对产品的了解和时间，89.5%的金属比重远远高于我们公司推荐的。这应该就是问题所在。于是我们马上建议了新的金属比重的Indium3.2.

焊锡膏中一般有50/50体积比的金属和助焊剂，重量比大约为90/10。 各个公司不同产品的金属含量比重都会有点差别。但正是这细微的差别，很可能就是产品性能最佳表现决定的关键。比如说3号金属粉和4号金属粉的差别，因为4号粉的表面积比3号粉多，需要更多的助焊剂来“清洗”金属球表面的氧化物，所以4号粉的金属比一般会比3号粉低一点点。金属比的不一样，也会使锡膏的viscosity黏度不同，这会影响印刷时的表现。

Cheers!

Pic:Indium Corporation

PS: 上周看了US Today报纸中的一篇报道“’Made in China’ benefits U.S.”这还是我第一次看见老美自己写出报道，公开说认识到了中国制造其实是在多方面对自己国家有利的；而不是以前老说的中国制造削弱了美国的制造业，抢走的美国的就业机会，等等。如果你看到报道上说的数据，每1美元中国制造的产品，有45美分是给了中国（产品的物料成本，中国人民的劳动力，土地，各种资源等），还是55美分是进美国人自己的口袋（营销，渠道，和售后服务）！！郎咸平是这方面的专家，好久没有看他的书了，最近要温故一下了。 

Last week I spent some time in the simulation lab with Eric Bastow, verifying the printing characteristics of our newest low temp metallization paste LT-918. Due to its current success with a variety of customers, we needed to take production capacity to the next level. New equipment was purchased to keep up with the demand, but there is always the chance that material may not perform the same when it is made in substantially larger batches. Our testing confirmed the printing characteristics of the material made on the new equipment surpassed that of previous batches. That’s good news for everybody.

As you can see from the picture, we used a standard printer designed for stencil printing solder paste onto electronic circuit boards. The printer was not the only similarity to solder paste printing though. An interesting characteristic of LT-918 is that it has a higher viscosity than most metallization pastes, which helps with print definition. The high viscosity of LT-918 helps it print like a solder paste, this is great for solder paste printers (like Eric and I, and many of you for that matter) from the SMT and semiconductor assembly industries.

In my opinion, LT-918 is the best metallization paste currently available for interconnecting thin-film cells. It has not only excelled in printing, it also has industry-leading resistivity scores, and has passed customer reliability testing including thermal cycling, damp heat stability, and accelerated UV tests. Much of the data that we can share will be available soon as a product brochure that we hope to have ready for you at EU-PVSEC in September.

• High thermal conductivity (33W/mK)
• Higher melting point than SAC alloys (221C)
• Low tensile stress, so suitable for large die (5800psi)
• Excellent thermal cycling properties (-55 to 125C)

1.  Preform (a specially-shaped solder piece) with TACflux® used to hold the preform and die in place
2.  Solder paste, which holds the die in place with no extra materials added 
3.  Soft solder die-attach wire, a fluxless type of solder wire, which is melted onto the substrate metallization under an inert cover gas, and the die directly mounted onto the molten solder pool, then allowed to cool.

Folks,

Many people have been infatuated by the price of gold in recent months, but the price of silver has also skyrocketed. In 2000 silver was about $3.00 per troy oz. In the eight years that followed, its price grew to $15/oz. Today it is trading at over $41/oz! This price is almost an all time high, except for the time when the Hunt brothers tried to corner the silver market in 1980. The aberration of their efforts jolted the silver price to just short of $50/oz, but it settled down to $11 or so after the Hunts came under margin call and other pressures.

Unfortunately, the dramatic price increase today, does not appear to be an aberration. Although we may hope that it will soon drop to more historic levels, we may not have reason to expect that it will.

Although not as dramatic, tin and copper have experienced significant prices increases as well. The price of tin has doubled in the last year to $15/pound and copper has increased from about $3/lb to $4.50.  These metals are obviously key ingredients in critical electronic materials such as solder pastes, solder bar, and solder preforms.

In addition, oil, which is used for most organic electronic materials such as PWB resins, flip chip underfill, and epoxy fluxes, has increased to $110/bbl - approaching its all time high of $145/bbl.

All of these price increases have a significant impact on the electronic materials supply chain. Although we are used to price decreases in the cost of our mobile phones and PCs, at this point in time, the price of the materials that go into these devices will be increasing.

As one materials supply chain executive commented at APEX, “It’s not like we can be clever and somehow work around the price increase of silver and these other materials, we have to pass it on to our customer, or go out of business.”

At the time of writing, the price of silver (Ag) was approaching the USD$50/tr.oz. (Troy ounce) level, and threatening to go higher. With 1 Troy ounce being 31.1grams, this makes the cost of pure silver ingot close to USD$1.60/gram.

Image from goldsilveroz.com

Materials costs are therefore a major consideration for anyone using silver in any form. Naturally, we are now seeing a few Power Semiconductor packaging houses evaluating the possibility of moving away from silver-filled epoxies for die-attach. The alternatives they are considering include the adoption of solder paste (or solder in some other form: wire / ribbon / preforms) versus a silver-filled epoxy.

Here are some thoughts on the Power Semiconductor assembly pros and cons, based on using solder paste as an alternative to silver-filled epoxies.

Good news (+)

+   Reduced materials costs
+   Improved pot-life / shelf-life *
+   Improved high temperature thermal-cycling
+   Strong, metallurgical joint formed between leadframe (substrate) / joining material / die
+   Improved thermal conductivity
+   Faster throughput (more units per hour, UPH)**
+   Easy clean-up ***
+   Does not wick onto NiPd surface to cause poor wire bondability

 * Although it is true that solder pastes are stored under refrigerated conditions, they do not require the -40C storage that is typical of silver-filled epoxies. 

 ** The dispense of solder paste is very rapid and can be done using multi-dot dispense heads. It undergoes rapid temperature reflow, versus the slow cure needed for metal-filled epoxies, which can be up to typically 1-3 hours, depending on the volume of silver epoxy.

 *** Because the solder paste flux does not cure like a polymeric material,  tubing and other conduits for the solder paste are easily cleaned out using common solvents, or can be simply purged with flux.


  ==================

Bad news (-)

-   Capital costs #
-   Adoption time / new process learning ##
-   Needs a solderable die surface
-   Voiding increase ####

 # The main cost-drivers here are:

- Reflow: Specialty reflow equipment is required for high temperature solders, such as
Heller or BTU reflow ovens

- Cleaning: If wirebonding is required after the reflow process, standard cleaning equipment and cleaning chemistry (aqueous or solvent-based) will be needed to remove flux residues

- Gas: Forming gas (H2/N2) or simple nitrogen may be needed to assist reflow.

Note that increasingly, for clip-bonding (non-wirebonding) applications using the new ultralow residue solder paste Indium9.32, even cleaning may not be needed, as the residue has been found to be compatible with compatible with a number of molding compounds in the industry.

 ## By partnering with a company like Indium Corporation with many years of experience in die-attach soldering, the ramp-up time can be significantly reduced.

 ### A solderable surface is usually a sequence of Ti / Ni / (Ag or Au) plated layers. The thickness of the silver (Ag) or gold (Au) precious metal layer is usually limited to 100nm (0.1microns). Compare this to a standard silver-epoxy bond line thickness (BLT) of 0.5-2mils (12-50microns).

 #### Acceptable voiding of less than 5% of the total die area is fairly easily achieved with good quality substrates and die-finishes.

  ==================

In closing, I am indebted to my friend and colleague Sehar Samiappan (Indium Corporation Area Technical Manager - South East Asia) for his insights.

Contact me to discuss this further.

Cheers!   Andy

这两年美国的西北部有越来越多的光伏太阳能公司在这里开设工厂，有些公司是前些年在加州硅谷地区把技术研发成功了，然后再把工厂开设在美国西北部（利用这里相对廉价的总成本，和联邦政府和州政府的补贴或投资的政策和条款）

在太阳能板子的组装方面，平时客户们问得最多的就是互联条和汇流带了(tabbing ribbon; bus ribbon)。这两种产品和普通的焊接带有一点区别，它们两一般是镀锡铜带。一般的客户都会有自己对互联条和汇流带的详尽规格说明(specifications)，比如说要求铜的规格是什么，镀锡的合金、厚度、误差范围(tolerance)，成品的宽度、厚度等。其中，与普通焊接带(solder ribbons)特别不同的是，互联条和汇流带一般有以下四点规格要求：

---Camber 曲弧度:简单来说，就是一条线拉直了，曲翘的程度不能超过多少。

---Elongation 延伸率: 一般有最小的百分比要求。

---Yield Strength 屈服强度: 材料开始产生宏观塑性变形时的应力。一般互联条要求的范围值比汇流带要求的范围值会低，毕竟每一段互联条要链接相邻太阳能板子的正反两面，要比较相对容易形变一点。

---Tensile Strength 拉伸强度: 是指材料产生最大均匀塑性变形的应力. 

Indium公司还提供各种太阳能溅射靶材(Sputtering Target)，太阳能低温焊锡膏(metallization paste)。 www.indium.com/solar

Pic：Indium Corporation

PS: 卖各种焊接产品给太阳能公司的生意不容易做啊。但是有机会，有潜在客户，总比根本没客户没机会好：-）最近有一个潜在大客户的进展很不错，让我顶着大肚子都往那里跑，常常为它忙乎着：-）

随着电子元器件组装微型化的趋势(miniaturization)，最近有越来越多的客户向我们咨询叠成封装的材料以及相关工艺(Package-on-Package；PoP)。

在向客户推荐PoP材料的时候，除非客户已经十分清楚自己要什么，我们一般会和他们详细介绍叠成封装焊锡膏PoP paste 和叠成封装助焊剂PoP flux具体是什么，分析各自的优缺点，然后让客户自己做决定。

Indium 公司的PoP paste (Indium9.88HF) 用的是5号金属粉，金属比重大概在80%-83%之间，根据是有铅还是无铅而定。 我们做过一系列的实验，和常规的SMT 3号粉和4号粉，各种金属比重的焊锡膏做比较，用5号粉在这个金属比重中做出来的PoP paste，各方面的性能最好。 Indium公司的PoP flux (Indium 89HF-LV) 也是根据各种实验结果都是最好的证实后， 才推出的。 通常检测PoP焊接材料， 可以做这三个实验： Transfer Test, Wetting Test, and Electrical Test. 具体的检测方法，Indium公司的Jim Hisert在他的论文中有详细描述。《Next Generation PoP Pastes for Electronics Assembly》

一般我个人比较喜欢推荐PoP paste，因为PoP paste能够提供extra solder。 PoP component本来就很薄，在焊接后回流的过程中十分容易“warpage 板翘”，那么component边缘部分就很有可能有一个上下之间很大的gap，导致根本无法形成良好的焊点。但是如果使用优良的PoP paste, paste中的extra solder metal 就能起到一个很好的“粘合剂”作用，即使有warage，也可以有一定的防御。 但是PoP flux在这方面就相对弱一点。

然而，PoP paste中的flux，因为要做很多功夫来清洗powder表面的氧化物，所以在回流过程中会有挺多的outgassing，这就很有可能导致空洞voiding 的产生。PoP flux相对而言，outgassing 就少很多，自然产生voiding的几率也小。

无论如何，优良的PoP paste and PoP flux，在防止wargage和voiding产生的defect方面，都是应该做得不错的。

Cheers!

Pic: Indium Corporation

Acknowledge to: Eric Bastow andJim Hisert with Indium Corporation