Example:

Figure 1: Example shown Indium8.9 flux with SAC lead-free alloy
The reason for approaching this subject is that often there has been some confusion in regards to the difference between max slope (a category reported on most profiling software) and the ramp rate listed on a data sheet. 
Figure 2: Max Slope
The max slope is very often attained in the first zone as the PCB moves from ambient temperature into the oven. In most cases the oven zone setting for the first zone is 100°C or better. The change in temperature between ambient and the first zone then is a minimum of 75°C (assuming 25°C as ambient) and so it’s easy to see that the greatest change in temperature (max slope) in most cases is typically found in the first zone
The focus of max slope is more from a component view point, to avoid thermal shock, usually 3°C/s is recommended as the upper limit
Figure 3: Ramp or Average Rate
The ramp rate may be better described as the rate (change in temperature over time) from ambient (room temperature) to peak. And is more practically used in a ramp to spike type profile
From the view point of the solder paste, the lower the ramp rate the better, usually 1-2°C/s. This is to drive off volatiles and help minimize solder defects such as solder balling, solder beading, and tombstoning. This rate becomes even more important as the solder paste deposit continually decreases in size, as we move to 0201’s and smaller discrete components and from 0.5mm pitch area array packages to 0.4mm and smaller. Due to this miniaturization, the observance of graping and head-in-pillow have become more common. The reflow process window is becoming very narrow and this attribute (ramp rate) has become as important as time above liquidus and peak temperature.
I'd love to discuss this with you, if this topic is affecting your SMT process. If you'd like, feel free to contact me.
My first step was to investigate the stencil design for these discrete components. Why? Because, since water soluble post-reflow residues (including solder balls & beads) are washed away, many customers will opt to place as much solder (1:1 ratio) as possible on the pads - to achieve a good solder joint. This is especially true for military or medical applications where a robust solder joint fillet is vital. However, because no-clean residues are typically not cleaned, the solder balls and solder beads remain in the flux residue and may produce electrical shorts.



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