Bus Ribbon

Today I received an interesting email that could be useful for my readers. Here goes:

“Dear Jim,

I saw your recent blog. I am in the process of prototyping a photovoltaic application. I am aware that Indium Corporation has a lead-free alternative for tabbing and bus wire. Can you comment on why the photovoltaic industry, specifically in the US, has not adopted this standard as a better non-toxic solution and what Indium Corporation has done to promote this alternative? I look forward to hearing your point of view!

Best Regards,”

That’s definitely an important question, what an ice breaker! This was my response:

“First of all, thank you for reading the blog and thank you for the thoughtful question.

What many people do not realize, is that there are actually a few different types of lead-free alternatives for cell tabbing. The 3 most common alloys for tabbing ribbon are :

• 96.5Sn/3.5Ag
• 57Bi/42Sn/1Ag
• 58Bi/42Sn

Here are the main reasons that people stick with Sn/Pb based tabbing ribbon coatings:

• Sn/Pb and Sn/Pb/Ag have been extensively proven with many different module designs  
  
• Indium (the metal) based alloys are quite expensive compared to Sn/Pb based alloys
• Sn/Ag melts at a higher temperature range, causing greater expansion of the base copper (and therefore greater coefficient of thermal expansion mismatches).
• Some people fear the melting point of Bi/Sn and Bi/Sn/Ag may be too low for their subsequent processes (such as lamination)

The key point I’d like to note is that there are companies currently using each one of these alternative, and finding them feasible in regards to cost and reliability. We promote the use of these alloys - I would personally like to see the 57Bi/42Sn/1Ag alloy take over the market. I like to see my customers making good modules and feeling good about the materials they use too!

All the best,

          ~Jim”

Later on in the day we discussed the technical aspects of using lead-free alloys and settled on Bi/Sn/Ag and GS-5454 as the go-to materials. It was great to have this conversation with someone focused on conscious material selection and eager to learn more about lead-free options.

What are your thoughts?

这两年美国的西北部有越来越多的光伏太阳能公司在这里开设工厂，有些公司是前些年在加州硅谷地区把技术研发成功了，然后再把工厂开设在美国西北部（利用这里相对廉价的总成本，和联邦政府和州政府的补贴或投资的政策和条款）

在太阳能板子的组装方面，平时客户们问得最多的就是互联条和汇流带了(tabbing ribbon; bus ribbon)。这两种产品和普通的焊接带有一点区别，它们两一般是镀锡铜带。一般的客户都会有自己对互联条和汇流带的详尽规格说明(specifications)，比如说要求铜的规格是什么，镀锡的合金、厚度、误差范围(tolerance)，成品的宽度、厚度等。其中，与普通焊接带(solder ribbons)特别不同的是，互联条和汇流带一般有以下四点规格要求：

---Camber 曲弧度:简单来说，就是一条线拉直了，曲翘的程度不能超过多少。

---Elongation 延伸率: 一般有最小的百分比要求。

---Yield Strength 屈服强度: 材料开始产生宏观塑性变形时的应力。一般互联条要求的范围值比汇流带要求的范围值会低，毕竟每一段互联条要链接相邻太阳能板子的正反两面，要比较相对容易形变一点。

---Tensile Strength 拉伸强度: 是指材料产生最大均匀塑性变形的应力. 

Indium公司还提供各种太阳能溅射靶材(Sputtering Target)，太阳能低温焊锡膏(metallization paste)。 www.indium.com/solar

Pic：Indium Corporation

PS: 卖各种焊接产品给太阳能公司的生意不容易做啊。但是有机会，有潜在客户，总比根本没客户没机会好：-）最近有一个潜在大客户的进展很不错，让我顶着大肚子都往那里跑，常常为它忙乎着：-）

It was a pleasure interviewing Pat Gallagher, who developed the first automated photovoltaic solar cell tabbing and stringing machine back in 1979. (Before I was even born!) Pat has seen the tabbing industry mature, and he was kind enough to help answer some questions about the process that I’ve grown to love. 

Jim: What were the initial design goals? How have they evolved over the years with customer’s needs?

Pat: Our primary goal was to replace variable hand labor in soldering with a machine and a process. That still holds today. Back then, solar cells were very expensive, thick, brittle, and not very efficient. So the biggest issue was to avoid breaking cells. Our first advice to the cell people was to turn the crystal 45 degrees to the bus bars so that the sides of the cell wouldn't break off along the solder joints. That little trick remains in place today.


Jim: Were the first machines designed to tab and string separately, or in a combined process?

Pat: Our first design was to make strings of cells in one shot. The two-step process, fronts then backs, was a holdover from hand soldering and there was no reason to do that anymore. Surprisingly, however, we ended up accidentally inventing the mechanized tabber on the way to creating a fully automated one-step stringer.

Jim: So that’s where the stand-alone tabber came from! I would have guessed it was the other way around. Have there been any changes to the heating method?

Pat: Oddly, the first thing we tried was induction heating. It was wonderful except that it took 5,000 watts to bring a small solar cell to temperature. It seemed rather wasteful, but that was the smallest industrial RF system available. Then we tried IR light, which also worked well. That's what we used in the first automated system.

Jim: Early tabbing ribbon must have been pretty crude. Have you noted anything that has changed with the copper or solder coating used over the years?

Pat: Basically, it's the same flat conductor that we started with in the 70's. The coating chemistry has changed dramatically. Taking cues from the electronics people, we started with lightly tinned copper and that was it. Solder was introduced on the cell so the ribbon did not need a heavy solder coating as is common now.

No-Lead (Pb-free) has been challenging mostly because the process window is smaller and simply hotter. The cells can be hurt if heat exposure is too long or too fast.

If you’d like to meet Pat (the President of Solar Automation) and learn more, you can email him by clicking here or visit the Solar Automation website.

Jon major recently joined the Indium Corporation as a Product Manager for Solar back-end assembly products. I greeted him with this impromptu interview.

Jim: First of all Jon, welcome. It’s great to have you as a new addition to the team!

Jon: Thank you Jim – it’s an exciting time to be at Indium Corporation and a fantastic time to be a part of the growing solar industry. I am extremely enthusiastic about my new position and am looking forward to making a positive contribution to the solar industry.

Jim: I noticed it didn’t take you long to get up to speed. Your time in Silicon Valley must have helped.

Jon: Coming from the electronics industry with a focus on product development, new product introduction, manufacturing, and external partner management, I am excited that my past experiences can contribute both to the industry and to Indium Corporation. After joining Indium only a few weeks ago, not only am I getting used to Upstate NY weather, but I have been immersing myself in solar with the goal of gaining a comprehensive understanding of:

•       Both rigid and thin-film technologies

•       Technology trends

•       Global and regional markets (EU, China, US, North America)

•       Solar supply chain (Silicon, wafers, cells, module, equipment, inverters, integrators)

•       Equipment manufacturers, contract manufacturers, and how we can collaborate with them to move the industry forward

•       Our products and pricing

•       Our current and future customers

•       Our short and long term opportunities

•       Our competition

•       Our roadmap

•       Our strengths, weaknesses, and threats

•       Our manufacturing capabilities and our QA process

•       Our sales channels, value proposition, key differentiators

•       All Indium processes

Jim: I know you've got solar products on your mind. Let our readers know a little bit more about your role here at Indium?

Jon: As a Solar Backend Product Manager I will focus (officially) on the business development and growth of Indium’s Solar Back End product offerings.  Now that sounds great but what does it actually mean? I could cut and paste my official job description but I prefer to explain it in my own words. As I think about the first part of that statement, “business development and growth…”, I see my role as:

–      Know the market, the customers, the product, and the competition

–      Develop relationships with the Indium team, reps, partners, equipment manufacturers, and, of course, customers

–      Write valuable data sheets, publications, and sales literature

–      Listen to our customers' needs and provide solutions

–      Manage schedules and orders with minimal surprises

–      Build cross-functional collaboration (sales, distribution, marketing, engineering, R&D, QA, production, management)

–      Never let down partners or customers

–      Support all functions of the organization, both internal and external

–      Deliver above & beyond commitments

–      Make great bets – on technology, customers, and opportunities

–      Understand the product life-cycle

–      Ship high quality, consistent product

The second part of that statement “..of Indium’s Solar Back End product offerings” is fairly straightforward. Of course this means I will focus on Indium’s current back end products (tabbing ribbon, bus ribbon, metallization paste (or as I prefer to call it – “grid ink”), flux and flux cored wire). With a product development background, this also means I have an opportunity to work with customers, partners, and R&D to develop and bring new products to market that will advance the module assembly industry – very exciting for me personally.

Ultimately, I think of my role as both building awareness of Indium’s products and superior technical support available to our customers as well as helping to shape our growing industry.

Jim: Okay Jon, you’ve had a while to settle in and get familiar with our Solar Team’s past and present – what are you planning for the future of module assembly?

Jon: Regarding the future of module assembly it’s a bit early to know for sure but I am excited about our low-temperature bismuth-containing alloys. These low temperature, lead-free, bismuth-containing alloys reduce the soldering process temperatures, thus reducing thermal stresses. I’m also working with the Indium production team to further reduce our tabbing and bus ribbon yield strength. A lower yield strength will reduce mechanical stress on cells during the assembly process. This is crucial to minimizing the possibility of microcracks and cell breakage during the solar module assembly process.

In closing, having lived in California for the last 10 years, I am not 100% familiar with our Upstate New York climate, and especially not all the snow shoveling. I see in my future a solar powered driveway heater!

Jon can be reached at jmajor@indium.com

I’ve been pulling some products together for the InterSolar tradeshow in July, and a thought occurred to me: “these tabbing ribbon kits for solar panel assembly are so interesting, I know someone at the show is going to want one”. If you’ve been in a booth at a tradeshow before it’s probably happened to you too – someone may have asked you for one of your display items, last pieces of literature, or maybe some ancillary equipment that you had at your booth. For argument sake, let’s say it’s the only sample of a hot new product at your booth, and the customer wants to purchase it with cash and walk away with it on the spot. (Equipment guys have been known to frequently sell the equipment they had brought to the show, but they send the machine after the show is over.) So what do you do if someone wants to purchase the item you have on display?   

A second question from a different perspective: as a customer, how would you feel if the vendor wouldn’t sell that one display item that you’d like to leave the show with?

I’m really excited about a new option for those of us who are prototyping solar assemblies or evaluating new tabbing ribbon materials. I’ve been waiting for something like this – everything you need to solder solar cells together in one package. The turn around time is key too – you may recall an older post where I learned how quickly these materials shipped.

On the website where these kits are offered, the description reads:

“Tabbing ribbon kits come with everything you need to evaluate how Indium Corporation materials will work with your solar cells and assembly process. The kits can be used to:
- Evaluate which tabbing ribbon size is best for your design
- Determine which flux is best for your operation
- Experiment with new solder coating alloys
- Assemble a few solar panels”

The tabbing ribbon kits come in 3 flavors:

- Standard Sn/Pb/Ag (62Sn/36Pb/2Ag)

- Pb-Free (96Sn/4Ag)

- Low Temp Pb-Free (58Bi/42Sn)

I have a feeling the Low Temp Pb-Free kits are really going to be the most popular of the 3 that are offered though. Application temperature ranges will determine which kit to use, but all three versions of the kits are said to offer similar base copper sizes and tolerances:
“The ribbon itself is industry standard CDA 110 (99.9% Cu) core flat wire, coated with a precisely controlled layer of solder. Each ribbon is manufactured using our proprietary softening process so you can increase the yield of your stringing process.” Basically, this means that the softer tabbing ribbon will help eliminate the breakage of thinned cells during the heating/cooling cycle.

It also includes some matching bus ribbon to complete your panel build. If you’re trying to find the right flux, this kit serves dually as a flux evaluation kit as well. The kit is loaded with VOC-Free flux, rosin-based flux, and resin-based tabbing fluxes. I prefer GS-5454 as a flux for most tabbing operations, but you can see how the others stack up as well.

Let me know how you like the kit after you try it out!

~Jim

(jhisert@indium.com)

在中國，現在還是厚膜太陽能光伏技術佔主導(Thick Film Solar PV)。所以，Indium公司相對成熟的太陽能產品中，也就是鍍錫銅帶（Tabbing Ribbon or Bus Ribbon）的生意機會比較多了。 

镀锡铜带是韌銅，單面或是雙面再鍍上一層含錫的合金薄層，用於焊接。常用的鍍錫層有：

• Sn63 Pb37
• Sn96.5 Ag3.5
• Bi46 Sn34 Pb20
• Bi58 Sn42
• Bi57 Sn42 Ag1

含有鉍(Bismuth Bi)鍍層的銅帶，適用于對高溫比較敏感的光伏太陽能板子的硬化，特別是薄膜技術的板子。



Video: Youtube

I should take a minute a publicly thank our solar tabbing ribbon engineers for doing an excellent job today. We needed 6 different tabbing ribbon and bus ribbon spools for a project - so I contacted production mid-morning. By the afternoon, I had all the material I needed re-spooled and delivered to my desk.  Wow! I know these guys are fast, but I didn’t expect it to be that instant.

Thanks guys!

~Jim

This blog has been in existence for a little over two years now, and we would like to thank our readers for the feedback and inquiries you have provided. I welcome your comments on what you would like from us. Leave a comment below, or email me at jhisert@indium.com.

And now a look back on past topics of interest:
 

Grid Ink, Silver Ink, Conductive Ink

Bismuth/Tin Tabbing Ribbon, A Low Temperature Pb-Free Alternative

Plated Metallization for C-Si Solar Cells

Increase Packing Density for Evaporation Crucibles

Photon’s 5th PV Tech Show 2010 USA

IPC Solar Standards Update

Solder Shelf Life as Explained by Eric Bastow

Tips to Speed Your Solder and Flux Selection

What's Happening in the Technical Service Department 

A Day in the Life of a Tech Guy

A Clean Laboratory

CIGS for Beginners

3rd Renewable Energy Expo 2009 in New Delhi, India

Solar Products and Representatives

Kleenex®, Google™, FedX®, CIGs?

Indium Solar Products Reunited

Trade Show Visitors Love the Ground Floor

Solar Product Data Sheets

Intersolar 2009 – What Barrier to CIGS Technology?

Concentrator Photovoltaic Systems - Will they reach 50% Efficiency?

Standards for Solar Panel Manufacturing

Solar Panel Certification: “Barrier and Benefit” Reviewed by Eric Bastow

Low Temperature Metallization Paste

What Will Your Interest Be At InterSolar? Meet the Bloggers And Let Us Know.

Share Your Solar Images

SAC vs. Sn/Ag for Solar Soldering

Solder Thickness for PV Interconnect

What is Bus Ribbon?

Standard PV Interconnect Ribbon Sizes

No-Clean Flux

Photovoltaics in EMS Sector

PV Interconnect Products

Eric Bastow - East Coast Technical Support

Mario Scalzo - West Coast Technical Support

Au/Sn Sputtering Targets

SMT Goes Solar

A Trip Down Memory Lane 

More Information About Metallization Paste

A year in the Life of a Solar Blog

CIG Target

23rd European Photovoltaic Solar Energy Conference and Exhibition

TCO choices for CIGS manufacturing 

CIGS Absorber Layer Electroplating

No Slump Metallization Paste

Meet the Bloggers

CIGS - Can sputtering make a breakthrough?

Fluxes for Soldering Tabbing Ribbon

Computer Brain vs. Solar Photovoltaic

Beam it down from space

Selection of the Optimum Lead-Free Solder for Solar Tabbing Ribbon

Record Makes Thin-Film Solar Cell Competitive with Silicon Efficiency

Why Thin-Film Solar Cells are Here to Stay

Hot Rooftops to Flashy Digital Cameras

Synchronize Your Solar Cell

Solar Conversion Efficiencies  

Government Support is the Key

It's Just a Beginning ...

Okay, I have a confession to make: I’ve always had a grudge against bismuth, ever since I started recommending thermal interface materials. It is the polar opposite of my favorite element (indium) – well, as much as a metal can be. These 2 elements (indium or bismuth) are added to almost every solder with a lower solidus temperature than Sn/Pb. The choice for most thermal interface applications that I have dealt with was indium or an indium alloy, but now I am starting to become very fond of my new friend bismuth for solar applications.

Bi/Sn and Bi/Sn/Ag are now available as a solderable coating for our Tabbing and Bus Ribbon. After getting a feel for this material, I must say I find it pretty nice to work with. Both alloys melt at 138-139degC, with the Bi/Sn/Ag having a greater tensile strength (which is not necessarily a good thing for tabbing ribbon). With a little bit of lab time I have isolated an existing flux that works very well with these alloys. So far GS-5454 has formed good solder bonds down to 160degC. This is great news, because it allows you to minimize the reflow temperature (and stresses) of your C-Si/tabbing ribbon interface. 

~Jim

A big ‘thank you’ to InterPV Magazine for printing our recent article “Tabbing and Bus Ribbon for Solar Assembly”.  They do an AWESOME job of publishing a magazine that is visually stunning.  I swear – it’s like reading a tech guy's version of National Geographic! 

This article was unique because it's actually a collection of blog posts about tabbing ribbon.  They all seem to fit well together, so it was fairly natural.  In that respect, the hard work was done ahead of time.

A reader of this blog recently mentioned: "I am interested in what products could be sold by manufacturer's representatives."  That is a large question, considering the evolution that we have come to expect in the solar industry.  To answer that question involves first breaking up the industry into 2 separate sections, front and back end solar assembly.  Front end assembly involves the process of making the solar cell.  Back end involves connecting cells together and assembling them to create a useable device.

Both front and back end products are going to be geared to the customer's technology.  For instance, if I was purchasing materials for a large thin-film manufacturing company and someone boldly offered me glass filled high-temperature metallization paste, I would tell them to come back when they know what they are talking about.  (In reality, I'd be nice – even though it's an incredibly ignorant mistake.)  With that in mind, let's focus on what back end products a representative might be offering for crystalline and thin film solar customers – assuming that back end begins after metallization:

• Outsourced Solar Cells
• Tabbing Ribbon
• Bus Ribbon
• Tabbing Flux
• Solder Paste
• Preforms
• Solder Wire
• Tacky-type Fluxes
• Tabbing Equipment
• Rework Equipment
• Test Equipment/Services
• Packaging Materials
• Junction Boxes
• Laminate Materials
• Silicone/Sealing Materials
• Passive Components
• Ovens
• Frames
• Gloves / Lab Coats / Safety Equipment

I probably left out as many possible line items as I included, but I hope you get the idea.  Feel free to add the ones I forgot in the comment section below.

~Jim

Metallization Paste, tabbing ribbon, bus ribbon, tabbing flux, targets, chemicals, and evaporation sources

One of the fun things about tradeshows is that you have a chance to see products that you would not normally see otherwise.  Similarly, it is always interesting to see a wide variety of products together in one place.  The picture here shows a range of Indium solar products all in one place.  Sure we get to see the products everyday – but to see everything together is pretty impressive.

~Jim

X-section of tabbing ribbon showing solder thickness

Solder thickness is important whether you are interested in tabbing ribbon, bus ribbon, or (most likely) both types of PV interconnect materials. In almost all tabbing/stringing applications, the solder coating on the interconnect ribbon provides 100% of the solder used to form a metallurgical bond on top of solar cells.  With this in mind, the solder coating should be more than just a 'shiny finish' on the tabbing ribbon – but what is the proper thickness for soldering?

Indium Corp. has been making precision solder coated ribbon for quite a long time (and not just for tabbing/stringing).  This experience has taught us how to control solder thickness, and also what thicknesses work in various applications.  If you would like to learn how solder coating thickness affects the reliability of your solar cell, email us at: solar@indium.com.

Bus Ribbon vs. Tabbing Ribbon (left to right)

Bus ribbon is a very specialized interconnect for photovoltaic modules.  Much like tabbing ribbon, bus ribbon is made of a copper ribbon or flat wire which is coated in solder.  The solder protects the surface of the copper from oxidation and provides a layer of solder to form a solder joint.  These solder-coated copper strips are used to channel current from the top and bottom of solar cells (tabbing/stringing) or to collect the electricity from these strings (bussing).

The main difference: bus ribbon is a bit wider, and sometimes thicker than tabbing ribbon.  You can think of tabbing ribbon as roads which travel across a solar cell, and bus ribbon as the highways that connect and tie them together.  Bus ribbon is larger in cross-section because it has more electrical current to carry.  To give you an idea of the size, bus ribbon is generally anywhere from 5mm-6mm wide, although some applications require bus ribbon more than twice as wide.

As bus ribbon becomes larger and larger, it is only natural to ask: "When will things need to change?"  When efficiencies and currents outgrow the physical constraints of bus ribbon, will module design change to meet the requirements?  Perhaps there will be a shift in the materials which are used instead – which would likely be even more expensive than a design change.  Either way, solder-coated copper bus ribbon has a long life ahead of it as the solar panel interconnection material of choice.

PV interconnect products have a lot of nicknames: tabbing ribbon, interconnect wire, bus bar, stringing ribbon, etc.  I wish I could say the dimensions are only as various as the names we use to describe them.  We look forward to working with you on custom PV interconnect projects though.  To speed the process, just email us at solar@indium.com with your specifications.  Along with copper thickness, width, and solder alloy and thickness, make sure to include all the criteria that are important to you.  That's one of the best reasons to work with us on your project – you can get exactly what you think will work best in your application.