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Recycling Solder Dross

Posted by Brook Sandy on Tuesday, November 8, 2011

Wave Solder PotAnyone who has used wave soldering to assemble PCBs knows about that chunky layer of metal that collects on the smooth surface of the molten solder. This is solder dross; it is composed of oxidized metals and impurities that collect as the molten solder contacts the air and manufacturing environment. This happens regardless of alloy and is a normal part of the process, often consuming up to 50% of the bar solder added to the solder pot. In the past, this dross was collected as waste and disposed of, but solder dross is more than 90% valuable metal. This value should be recovered.

Nowadays, typically, this dross is collected and returned to a metals supplier for recycling. Indium Corporation now offers two programs for recycling solder dross. The first program involves simply sending back dross waste in return for a portion of the metal value as a credit. The second option involves sending back dross, which is converted to bar solder (within the original spec) and returned, with you paying only a fee for processing. When dross arrives, regardless of which program is chosen, it is electrolytically refined and the pure metals are recovered and converted back into usable bar solder. Often, this reclaimed/recycled metal has a better purity than virgin metal.

Dross is not the only form of solder that can be recycled. For instance, when changing to a different alloy in a wave soldering process, the entire solder pot will need to be emptied. The old alloy can be collected and recycled, lowering the amount of capital necessary to switch alloys. Bar solder and wire that have not been used within the shelf life can also be recycled to get back some of their value.

Contact me if you want to discuss this.

Dross Recycling and Solder Bar
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The Power of the Universe

Posted by Brook Sandy on Wednesday, June 8, 2011

Puyehue volcano source GizmodoIn the last few months, it seems I have been often reminded how powerful the universe can be. Today, checking my email, I found some fantastical photos of Puyehue volcano, in Chile, erupting. This volcano, which had lain dormant for half a century, erupted spectacularly today, 6-6-11. This is merely one of many such coincidences lately. This picture, just one of three breathtaking photos, once again reminds me that the universe is surprising and full of wonder.

Things in my life have been pretty wonderful lately as well. I love my career, and my new husband. As the flowers have bloomed this spring, so has everything in my life. I am overwhelmed with gratitude for my friends and family and community.

Of course, this also reminds me that the universe provides. Whatever you want… if you ask the universe for it; pursue it in your actions every day; and have patience and faith that it will come to you. It will. 

Just a short bit of inspiration for the day. As my father quotes from Bill & Ted: “Be excellent to each other.”

Peace, Brook

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Metallurgy as Modern Alchemy: Bismuth

Posted by Brook Sandy on Wednesday, November 17, 2010

Although most scientists today feel that alchemy has been widely discredited, and I have been taught to agree, the idea of it is whimsical and exhilarating.  Of course, I don’t have a hope of changing the makeup of bismuth or transforming it into another metal, but in a modern way, it’s very interesting how bismuth can be used to change the properties of other metals significantly - through alloying. In my last post on bismuth, I outlined its physical properties, some of which I find rather unusual. The main reason I originally researched bismuth was because of its viability for use as a low temperature Pb-free alloy.

BACKGROUND:
I'm not an alchemist like Newton, I can't transmute bismuth to gold like Seaborg, but I can use bismuth and metallurgy to transform an alloy.

I just read a fascinating article about Sir Isaac Newton titled, “Moonlighting as a Conjurer of Chemicals”. Newton is widely regarded as one of the most important people in the history of science, and he was very devoted to his work. The revelation in this article about the depth of his interest in alchemy left me somewhat awestruck. In my previous reading about Newton, I remember perhaps a mention of his interest in alchemy, but I guess I figured it was because science and alchemy, at that time, were fairly closely related. As scholars are starting to translate more of his diaries, they are discovering that his passion was alchemy and he saw it as the path to complete control over the natural world.  

I suppose if it was still socially acceptable to be an alchemist that is what I would have wanted to be; it just never seemed to be a viable option. What I have chosen to do now kind of makes sense considering chemistry/metallurgy is about as close as you can get nowadays. 

Reading this article reminded me of some interesting information I had come across while researching bismuth a couple months ago; namely that, although bismuth wasn’t one of the seven central metals in alchemy, it has an "alchemical" symbol (#52 in the image to the left) and was frequently used, although it’s not known for what purpose. I also came across this bit of information:

“In 1980, a scientist named Glenn T. Seaborg was able to transmute a minute quantity of bismuth into gold at the Lawrence Berkeley Laboratory, via nuclear collisions.” 

Seaborg is a fascinating scientist in his own right and discussion about him could fill quite a number of blog posts. Is it possible that alchemists underestimated bismuth and should have focused more on turning it into gold?

BACK TO MODERN TECHNOLOGY:
The eutectic alloy of 58Bi/42Sn has been used since the Pb-free transition as a low temperature (138°C liquidus) option for soldering products used at ambient temperatures - such as consumer electronics.  Note the low melting temperature of this alloy, despite the individual melting temperatures of bismuth and tin, 271°C and 232°C, respectively. Although bismuth is typically known to be quite brittle, this alloy has been shown to perform similarly to the SnPb eutectic solder (in response to a comment on my last post, for further data-based information, please feel free to contact me directly). In cases where more ductility is desirable, 1% silver can be added, further improving thermal shock and fatigue resistance. Perhaps the similarity in performance makes sense because of bismuth’s proximity (right next to) lead on the periodic table, although they differ in several other qualities such as toxicity.

The more I learn about bismuth, the more interested I become. Now if only I could find some in-depth alchemical information about it from Sir Isaac Newton.

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It's Awesome to be a Young Professional

Posted by Brook Sandy on Monday, November 15, 2010



Tomorrow is the first networking event for the Mohawk Valley Young Professionals! This group was started to provide a place for young professionals to get together, network, share ideas and successes, and support the community through volunteerism. I’m excited to get things rolling and want to extend an invitation to any other young professionals in the Mohawk Valley region to please join us between 5:30 and 8:30 tomorrow, Tuesday November 16th for our first networking happy hour. We will be at Hotel Utica sharing food, drinks, and music. I hope to see you there!

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Bismuth: My New Friend

Posted by Brook Sandy on Monday, October 11, 2010
Bismuth CrystalsLately I have been researching a bunch of things, one of my favorite topics being soldering alloys. For a long time most solder (nearly all) was comprised of tin-lead eutectic alloy. Everyone was very comfortable using this alloy until RoHS and other changes in regulations started to tip the scales in favor lead-free alloys, requiring a new approach to soldering materials and processes. The industry, since then, has tended toward using tin-silver-copper (SAC) alloys of various compositions; however none have lived up to all of the properties tin-lead solder offered. In fact, one of the most disruptive characteristics of SAC alloys has been the increased temperature required for reflow, therefore the increased temperature requirements for components and boards.

To achieve enhanced properties, and fill niches that SAC fails to satisfy, research is being done on the addition of dopants to SAC solders. This is where I started to become intrigued with bismuth. The more I read, it seemed, the more I was running across this odd metal that I didn’t know too much about (remember, I’m new to the realm of solder). This prompted a small search that yielded some fascinating facts:

·         Bismuth is a brittle metal, often displaying a pinkish hue due to its surface oxide

·         Bismuth has a low melting temperature (271°C)

·         Bismuth expands upon solidification, kind of like water

·         Bismuth is the heaviest non-radioactive (perhaps considered slightly radioactive), naturally occurring metal on the periodic table

·         Bismuth is not usually mined by itself, rather a bi-product of lead, tin, silver, and other metals

·         Bismuth is the most diamagnetic of all metals

·         Bismuth has the lowest thermal conductivity of all metals other than mercury

·         Bismuth crystals exhibit a reflective rainbow of colors because of the varying thickness of oxide on the surface

·         Bismuth subsalicylate, which is the active ingredient in Pepto Bismol, is outlawed in France (due to outdated concerns about it causing encephalopathy)
Bismuth Crystals
The most interesting attribute of bismuth, from an electronics materials perspective, is that, when alloyed with other metals, it creates low-melting temperature alloys. In particular, when alloyed with tin at the eutectic composition, the alloy melts at 138°C and displays properties comparable to the tin-lead eutectic. The brittleness of bismuth is the main concern when using it for soldering; however, this effect can be mitigated by the addition of more malleable metals to the alloy, such as silver. Many of the popular bismuth-containing alloys contain a high percentage of bismuth, but work is being done with lower concentrations, yielding different properties. Although the melting temperature will not be lowered as dramatically, bismuth at lower concentrations has the potential to enhance performance in drop testing and thermal shock.

Given rising concerns over the cost of metals, bismuth may become more of a contender in the search for alternative solder alloys. I’ve come to think of bismuth as my new friend, because I think that it offers a different avenue for exploration and seems promising for enhanced low-temperature alloys.
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My Journey to Become an Expert in PCB Assembly Materials

Posted by Brook Sandy on Wednesday, August 11, 2010

Welcome! I am a chemical engineer experienced in an R&D setting and jumping into a new position in marketing here at Indium Corporation. Initially, in this blog, I will focus on my journey getting started, learning all the new facets of the business here, and transitioning from my former R&D mindset into something more outward facing and communications-based. I am relatively new to this world of social networking too, so I’m sure there will be plenty of growth in that direction as well. Hopefully, you will enjoy taking this journey with me, learning vicariously. I would certainly appreciate any pointers from you. 

Officially my job title is “Product Support Specialist”.  I’m learning that it means a lot of things, for example, being an expert in PCB assembly, the different products that are used for PCB assembly, and being able to convey that useful information to everyone that is interested. “Everyone” really could be anyone in this case: existing customers, potential customers, customers that haven’t even thought about how solder paste or another product might make their process easier, people who just have an interest in electronic materials… and people here at Indium, R&D, production, our sales team, and the list goes on. In time this blog (with any luck) will be a good resource for a lot of helpful information to all of these people.

As I am completing my first week here at Indium, I am feeling very optimistic about my new position and my capacity to contribute. Overall, this week has been like riding a wave of information, and just trying to scoop up as much as I can. I have been surprised by how much my previous experience in electronics materials is helping me. Even though the materials here are significantly different, I have been exposed to a lot of the same processes before (screen printing, mixing, metal powders, etc.), so I just have to make the mental links and note the differences. For instance, I was fascinated, while touring one of our manufacturing facilities yesterday, that we are using the same mixer I used in my former company’s pilot lab, just about 20 times larger. Also, we are packaging some of the material in the same cartridges and syringes I had previously filled by hand on so many occasions.

 

On a more personal note: Before starting Monday, I had mostly been filled with a sense of gratitude for having found a job that I really love, and a little bit with some apprehension about fitting into a new role, living up to all of the expectations (from myself, my co-workers, my new boss…). I suppose a long period of searching for employment, with all of the probing and feelings of rejection and such, really does change one’s perspective of their competencies. It has been difficult in the past months listening to the news and hearing reports of unemployment numbers staying the same or getting worse, and in addition having benefits for unemployment on shaky ground. In some ways it felt like people who were still employed might not understand how difficult it can be to find a job, even a job that doesn’t live up to the expectations one might have had 5 years ago. I just thought that I should note that there is still very much reason to hold on to hope: it is possible to find a wonderful job that fits your qualifications, and continue on after all of this economic turmoil. What was most important during my time searching was to keep searching for that job that would further my career the way I wanted it to, to keep applying to positions that might seem out of reach at the time, and to not get discouraged, because despite all of the unanswered emails and resumes, only ONE needs to come through… and that one could be awesome. Since Monday, of course, my doubts have been fading quickly, and I am still filled with that sense of gratitude, which I don’t think I would have appreciated without having gone through these tumultuous times.

 

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